Publikationen – Prof. Dr. Uwe Rosenthal

303.Hinz A, Kuzora R, Rosenthal U, Schulz A, and Villinger A. CHEMISTRY – A EUROPEAN JOURNAL, 2014, 20, 14659-14673. Activation of Small Molecules by Phosphorus Biradicaloids.
302.Roy S, Rosenthal U, and Jemmis ED. ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47, 2917-2930. Metallacyclocumulenes: A Theoretical Perspective on the Structure, Bonding, and Reactivity.
301.Heinig S, Woehl A, Mueller W, Al-Hazmi MH, Mueller BH, Peulecke N, Rosenthal U. CHEMCATCHEM, 2014, 6, 514-521. Influence of Ph2PN(R)P(Ph)N(R)H (R=c-Hex, iPr) Ligand Substituents, Modifier, and Process Parameters on Reaction Kinetics of a Chromium-based Catalyst for the Selective Trimerization of Ethylene.
300.Haehnel M, Spannenberg A, Rosenthal U. ACTA CRYSTALLOGRAPHICA SECTION E: STRUCTURE REPORTS ONLINE, 2014, 70, m16. Bis([m]2-isopropylimido-[kappa]2N:N)bis[([eta]5-cyclopentadienyl)(ethenolato-[kappa]O)titanium(IV)].
299.Haehnel M, Schubert K, Becker L, Arndt P, Spannenberg A, and Rosenthal U. ZEITSCHRIFT FÜR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640, 2532-2536. Reactions of Group 4 Metallocenes with N,N'-Diphenylformamidine – Hydrogen Generation versus Oxidative Addition.
298.Haehnel M, Priebe JB, Yim JCH, Spannenberg A, Brueckner A, Schafer LL, Rosenthal U. CHEMISTRY – A EUROPEAN JOURNAL, 2014, 20, 7752-7758. Four-Membered Heterometallacyclic d0 and d1 Complexes of Group 4 Metallocenes with Amidato Ligands.
297.Haehnel M, Arndt P, Spannenberg A, and Rosenthal U. ZEITSCHRIFT FÜR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640, 893-897. Synthesis and Characterization of Titanium 7-Azaindolato Complexes and their Lithium Precursors.
296.Burlakov VV, Bogdanov VS, Arndt P, Spannenberg A, Lyssenko KA, Baumann W, Minacheva MK, Strunin BN, Rosenthal U, Shur VB. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 751, 390-398. Interaction of the five-membered zirconacyclocumulene complex Cp2Zr(η4-tBuC4tBu) with acetylenes. Synthesis of zirconacyclopentadienes and seven-membered zirconacyclocumulenes.
295.Burlakov VV, Becker L, Bogdanov VS, Andreev MV, Arndt P, Spannenberg A, Baumann W, and Rosenthal U. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014, 5304-5310. Reactivity of a Seven-Membered Zirconacyclocumulene towards CN Multiple Bonds – Formation of Metallaheterocycles by Insertion of C≡N and C=N Groups.
294.Becker L, Spannenberg A, Arndt P, Rosenthal U. ACTA CRYSTALLOGRAPHICA SECTION E: STRUCTURE REPORTS ONLINE, 2014, 70, m57. (Cyanido-KC)(2,2-diphenylacetamido-K2N,O)bis(n5-pentamethylcyclopentadienyl)zirconium(IV).
293.Becker L, Strehler F, Korb M, Arndt P, Spannenberg A, Baumann W, Lang H, Rosenthal U. CHEMISTRY – A EUROPEAN JOURNAL, 2014, 20, 3061-3068. Unusual Nitrile–Nitrile and Nitrile–Alkyne Coupling of Fc-C≡N and Fc-C≡C-C≡N.
292.Becker L, Arndt P, Spannenberg A, and Rosenthal U. CHEMISTRY – A EUROPEAN JOURNAL, 2014, 20, 12595-12600. Reactions of rac-(ebthi)M(h2-Me3SiC2SiMe3) (M=Ti, Zr) with Aryl Nitriles.
291.Àrias Ò, Petrov AR, Bannenberg T, Altenburger K, Arndt P, Jones PG, Rosenthal U, Tamm M. ORGANOMETALLICS, 2014, 33, 1774-1786. Titanocene and Zirconocene Complexes with Diaminoacetylenes: Formation of Unusual Metallacycles and Fulvene Complexes.
290.Altenburger K, Baumann W, Spannenberg A, Arndt P, and Rosenthal U. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014, 5948-5957. Coordination Behavior and Reactivity of α-Heterosubstituted Trimethylsilylalkynes at Titano- and Zirconocene.
289.

L. Becker, V. V. Burlakov, P. Arndt, A. Spannenberg, W. Baumann, H. Jiao, U. Rosenthal Chemistry  – A European Journal  2013, 19, 4230-4237. Reactions of Group 4 Metallocene Complexes with Mono- and Diphenylacetonitrile: Formation of Unusual Four- and Six-Membered Metallacycles.

288.S. Heinig, A. Wöhl, W. Müller, M. Al Hazmi, B. H. Müller, N. Peulecke, U. Rosenthal, ChemCatChem 2013, 5, 3107-3113. Influence of Substituents in Ligands Ph2PN(R)P(Ph)N(R)H (R = c-Hex, iPr), Modifier and Process Parameters on the Reaction Kinetics of the Chromium-based Catalyst for the selective Ethylene Trimerization.
287.M. Haehnel, A. Spannenberg, U. Rosenthal, Acta Cryst. 2013, 69, m651. (m3-Hydrido)[m3-2-(trimethylsilyl)ethylidyne-k3C1:C1:C1]tetrakis[(h5-cyclopentadienyl)cobalt(II)].
286.M. Haehnel, S. Hansen, K. Schubert, P. Arndt, A. Spannenberg, H. Jiao, U. Rosenthal, J. Am. Chem. Soc. 2013, 135, 17556-17565. Synthesis, Characterization and Reactivity of Group IV Metallocene Bis(diphenylphosphino)acetylene Complexes – A Reactivity Study.
285.S. Heinig, A. Wöhl, W. Müller, M. Al Hazmi, B. H. Müller, N. Peulecke, U. Rosenthal, ChemCatChem 2013, 5, 3107-3113; The Effect of Substituents in PNPN-H Ligands on Activity and Selectivity of a Chromium-Based Catalyst System for Highly Selective Ethylene Trimerization.
284.M. Haehnel, J. C.-H. Yim, L. L. Schafer, U. Rosenthal, Angew. Chem. 2013, 125, 11626-11630; Angew. Chem. Int. Ed. 2013, 52, 11415-11419. Facile Access to Tuneable Schwartz´s Reagents – Oxidative Addition Products from the Reaction of Amide N-H-Bonds with Reduced Zirconocene Complexes.
283.L. Becker, P. Arndt, H. Jiao, A. Spannenberg, U. Rosenthal, Angew. Chem. 2013, 125, 11607-11611; Angew. Chem. Int. Ed. 2013, 52, 11396-11400, Nitrile-Nitrile C–C Coupling at Group 4 Metallocenes to 1-Metalla-2,5-diaza-cyclopenta-2,4-dienes: Synthesis and Reactivity.
282.V. V. Burlakov, V. S. Bogdanov, P. Arndt, A. Spannenberg, K. A. Lyssenko, W. Baumann, M. Kh. Minacheva, B. N. Strunin, U. Rosenthal, V. B. Shur, J. Organomet. Chem. 2013, dx.doi.org/10.1016/j.jorganchem.2013.07.026. Interaction of the five-membered zirconacyclocumulene complex Cp2Zr(η4-ButC4But) with acetylenes. Synthesis of zirconacyclopentadienes and seven-membered zirconacyclocumulenes.
281.K. Altenburger, J. Semmler, P. Arndt, A. Spannenberg, A. Villinger, W. W. Seidel, U. Rosenthal, Eur. J. Inorg. Chem. 2013, 4258-4267. Examples for different Reactions of Benzylsulfuryl-substituted Alkynes with Complexes of Ti(II) and Co(I).
280.M. Gongoll, B. H. Müller, S. Peitz, B. R. Aluri, N. Peulecke, A. Spannenberg, U. Rosenthal, M. Al Hazmi, A. Wöhl, W. Müller, Phosphorus, Sulfur, and Silicon. 2013, 188, 1845-1854. Synthesis of differently substituted N- and P-aminodiphosphinoamine PNPN-H Ligands.
279.T. Beweries, U. Rosenthal, Nat. Chem. 2013, 5, 649-650. METALLACYCLES – Breaking the rules.
278.K. Altenburger, P. Arndt, A. Spannenberg, W. Baumann, U. Rosenthal, Eur. J. Inorg. Chem. 2013, 3200-3205. Synthesis and Characterization of selected Group 4 Metallocene Complexes with 1,2-bis(4’,4’,5’,5’-tetramethyl[1’,3’,2’]dioxaborolan-2’-yl)acetylene.
277.V. V. Burlakov, K. A. Lyssenko, A. Spannenberg, W. Baumann, P. Arndt, V. B. Shur, U. Rosenthal, Inorg. Chim. Acta 2013, 401, 76-80. Reactivity of Functionalised Decamethyltitanocenes: Synthesis and Structure of Chiral Monocyclopentadienyl Titanium Halogenides.
276.M. Haehnel, S. Hansen, J. B. Priebe, A. Spannenberg, P. Arndt, A. Brückner, U. Rosenthal, Chem. Eur. J. 2013, 19, 7568-7574. Highly Strained Heterometallacycles of Group 4 Metallocenes with Bis(diphenylphosphino)methanide-Ligands.
275.Outside Cover: L. Becker, V. V. Burlakov, P. Arndt, A. Spannenberg, W. Baumann, H. Jiao, U. Rosenthal, Chem. Eur. J. 2013, 19, 4230-4237. Reactions of Group Four Metallocene Complexes with Mono- and Diphenylacetonitrile: Formation of Unusual Four- and Six-membered Metallacycles.
274.Review with Backside cover: T. Beweries, M. Hähnel, U. Rosenthal, Catal. Sci. & Technol. 2013, 3, 18-28. Recent advances in the chemistry of heterometallacycles of group 4 metallocenes.
273.M. Klahn, A. Spannenberg, U. Rosenthal Acta Crystallographica Section E – Structure Reports Online 2012, E68, o1261. 2-Vinylpyridine-tris(pentafluorophenyl)-borane hexane monosolvate.
272.M. Haehnel, K. Altenburger, A. Spannenberg, P. Arndt, U. Rosenthal, Acta Crystallographica, Section E: 2012, E68, m1425. Di-μ-sulfido-bis{[rac-1,2-bis(η5-4,5,6,7-tetrahydroinden-1-yl)ethane]zirconium(IV)} toluene monosolvate.
271.M. Hähnel, M. Ruhmann, T. Beweries, S. Roy, T. Beweries, P. Arndt, A. Spannenberg, A. Villinger, E. D. Jemmis, A. Schulz, U. Rosenthal, J. Am. Chem. Soc. 2012, 134, 15997-15991. Reactions of Titanocene Bis(trimethylsilyl)acetylene Complexes with Carbodiimides – An Experimental and Theoretical Study of Complexation vs. C-N Bond Activation.
270.K. Kaleta, F. Strehler, A. Hildebrandt, P. Arndt, H. Jiao, T. Rüffer, A. Spannenberg, H. Lang, U. Rosenthal, Chem. Eur. J. 2012, 18, 12672-12679. Synthesis and Characterization of Multiferrocenyl Substituted Group 4 Metallocene Complexes.
269.S. Kohrt, S. Hansen, H.-J. Drexler, Uwe Rosenthal, A. Schulz, D. Heller, Inorg. Chem. 2012, 51, 7377-7383. Molecular Vibration Spectroscopy Studies on Novel Trinuclear Rhodium-7-Hydride Complexes of the General Type {[Rh(PP*)X]3(μ2-X)3(μ3-X)}(BF4)2 (X = H, D).
268.M. Haehnel, S. Hansen, A. Spannenberg, P. Arndt, T. Beweries, U. Rosenthal, Chem. Eur. J. 2012, 18, 10546-10553. Highly Strained Heterometallacycles of Group 4 Metallocenes with Bis(diphenylphosphino)amide-Ligands.
267.K. Kaleta, M. Kessler, T. Beweries, P. Arndt, A. Spannenberg, U. Rosenthal, Eur. J. Inorg. Chem. 2012, 3398-3393. Different Inertness of Titanocene [Cp2Ti] and Decamethyltitanocene [Cp*2Ti] in Reactions with N,N-Bis(trimethylsilyl)sulfurdiimide: Elimination of Tetramethylfulvene and Formation of Half-Titanocene Complexes.
266.M. Klahn, A. Spannenberg, U. Rosenthal Acta Cryst. 2012, E68, o1549. Tris-tert-butylphosphonium tris(pentafluorophenyl)hydroxylborate.
265.M. Klahn, A. Spannenberg, U. Rosenthal Acta Cryst. 2012, A46, 194-201. Vinylpyridine tris(pentafluorophenyl)borane adduct.
264.B. H. Müller, N. Peulecke, A. Spannenberg, U. Rosenthal, M. H. Al-Hazmi, R. Schmidt,[ Wöhl, W. Müller, Organometallics 2012, 31, 3695-3699. Synthesis and Reactions of the Homoleptic Chromium(II)bis-amide [Ph2PN(iPr)P(Ph)N(iPr)-]2Cr with Relevance to a Selective Catalytic Ethene Trimerization System to 1-Hexene.
263.Cover: U. Rosenthal, M. Kessler, S. Schüler, D. Hollmann, M. Klahn, T. Beweries, A. Spannenberg, A. Brückner, U. Rosenthal, Angew. Chem. 2012, 124, 6377-6380. Lichtinduzierte Ti-O-Aktivierung in einem Decamethyltitanocendihydroxido-Komplex – Einblicke in die Elementarschritte der Wasserspaltung. Angew. Chem. Int. Ed.  2012, 51, 6272-6275, Photo-assisted Ti-O activation in a decamethyltitanocene dihydroxo complex - Insights into the elemental steps of water splitting.
262.S. Hansen, M. Klahn, T. Beweries, A. Spannenberg, U. Rosenthal, ChemSusChem. 2012, 5, 656-660. An intermolecular heterobimetallic system for photocatalytic water reduction.
261.S. Roy, E. D. Jemmis, A. Schulz, T. Beweries, U. Rosenthal, Angew. Chem. 2012, 124, 5442-5446. Theoretische Studien zu einem viergliedrigen Metallacycloallen, stabilisiert durch eine ungewöhnliche Übergangsmetall-Kohlenstoff-Bindung; Angew. Chem. Int. Ed. 2012, 51, 5347-5350. Theoretical Evidence of the Stabilization of an Unusual Four-Membered Metallacycloallene by a Transition-Metal Fragment.
260.U. Rosenthal, Angew. Chem. 2012, 124, 2326; Angew. Chem. Int. Ed.  2012, 51, 2280. Autoren-Profile.
259.N. Peulecke, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Cryst. 2012, E68, o11252. 4-Bis(diphenylphosphanyl)-1,1,2,3,3,4-hexaphenyl-1,3-diphospha-2,4-diboracyclobutane tetrahydrofuran Sesquisolvate.
258.M. Klahn, U. Rosenthal, Organometallics 2012, 31, 1235-1244. An Update on Recent Stoichiometric and Catalytic C–F Bond Cleavage Reactions by Lanthanide and Group 4 Transition Metal Complexes.
257.N. Peulecke, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Crystallographica E68, 2012, m119. Tetracarbonyl-[bis(diphenylphosphanyl)tetramethyldisiloxane-κ2P,P']-chromium(0).
256.R. R. Aysin, L. A. Leites, V. V. Burlakov, V. B. Shur, T. Beweries, U. Rosenthal, Eur. J. Inorg. Chem. 2012, 922-928. Peculiarities of Vibrational Spectra and Electronic Structure of the Five-Membered Metallacyclocumulenes of the Group 4 Metals.
255.V. V. Burlakov, V. S. Bogdanov, K. A. Lyssenko, A. Spannenberg, P. V. Petrovskii, W. Baumann, L. I. Strunkina, M. Kh. Minacheva, B. N. Strunin, P. Arndt, U. Rosenthal, V. B. Shur, Russian Chemical Bulletin; International Edition 2012, 165-173. Interaction of the Negishi reagent Cp2ZrBu2 with 1,4-bis(tert-butyl)butadiyne.
254.

Cover: K. Kaleta, M. Ruhmann, O. Theilmann, S. Roy, T. Beweries, P. Arndt, A. Villinger, E. D. Jemmis, A. Schulz, U. Rosenthal, Eur. J. Inorg. Chem. 2012, 611-617. Experimental and Theoretical Study of Unusual Four-Membered Metallacycles from Reactions of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes with the Sulfurdiimide Me3SiN=S=NSiMe3.

253.K. Kaleta, A. Hildebrandt, F. Strehler, P. Arndt, H. Jiao, A. Spannenberg, H. Lang, U. Rosenthal, Angew. Chem. 2011, 123, 11444-11448. Ferrocenylsubstituierte Metallacyclen des Titanocens – Oligocyclopentadienylkomplexe mit vielversprechenden Eigenschaften; Angew. Chem. Int. Ed. 2011, 50, 11248-11252. Ferrocenyl Substituted Metallacycles of Titanocenes – Oligocyclopentadienyl Complexes with Promising Properties.
252.S. Roy, E. Jemmis, M. Ruhmann, A. Schulz, K. Kaleta, T. Beweries, U. Rosenthal, Organometallics 2011, 30, 2670-2679. Theoretical Studies on the Structure and Bonding of Metallacyclocumulenes, -cyclopentynes, and –cycloallenes.
251.Inside Cover Picture: T. Beweries, S. Hansen, M. Kessler, M. Klahn, U. Rosenthal, Dalton Trans. 2011, 40, 7689-7692. Catalytic Dehydrogenation of Dimethylamine Borane by Group 4 Metallocene Alkyne Complexes and Homoleptic Amido Compounds.
250.T. Beweries, R. Kuzora, U. Rosenthal, A. Schulz, A. Villinger, Angew. Chem. 2011, 123, 9136. [P(μ-NTer)]2: ein hochtemperaturstabiles Diradikaloid; Angew. Chem. Int. Ed. 2011, 50, 8974; [P(μ-NTer)]2: A Biradicaloid That Is Stable at High Temperature (Hot Paper).
249.T. Beweries, J. Thomas, M. Klahn, D. Heller, A. Schulz, U. Rosenthal, ChemCatChem 2011, 3, 1865-1868. Catalytic and Kinetic Studies of the Dehydrogenation of Dimethylamine Borane with an iPr Substituted Titanocene Catalyst.
248.Book: T. Beweries, U. Rosenthal, Science of Synthesis Knowledge Update 2011/4. Recent updates in the organometallic chemistry of group 4 metallocene complexes with bis(trimethylsilyl)acetylene.
247.N. Peulecke, S. Peitz, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Cryst. 2011, E67, o1741. (Isopropylamino)(methyl)diphenylphosphonium iodide.
246.N. Peulecke, B. R. Aluri, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Cryst. 2011, E67, o1474. N,P,P-Triisopropylphosphinic amide.
245.V. V. Burlakov, P. Arndt, A. Spannenberg, U. Rosenthal, Acta Crystallographica E 2011, 67, m629. Tris(η5-cyclopentadienyl)hafnium(III).
244.K. Kaleta, M. Ruhmann, O. Theilmann, T. Beweries, S. Roy, P. Arndt, A. Villinger, E. D. Jemmis, A. Schulz, U. Rosenthal, J. Am. Chem. Soc. 2011, 133, 5463-5473. Reactions of Group 4 Metallocene Alkyne Complexes with Carbodiimides: Experimental and Theoretical Studies of the Structure and Bonding of Five-Membered Hetero-Metallacycloallenes.
243.V. V. Burlakov, Y. V. Nelyubina, K. A. Lyssenko, V. B. Shur, P. Arndt, W. Baumann, U. Rosenthal, Inorg. Chem. Commun. 2011, 14, 975-977. Synthesis and Crystal Structure of the First Five-membered ansa-Metallacyclocumulene rac-(ebthi)Zr(η4-t-Bu-C4-t-Bu).
242.S. Peitz, N. Peulecke, B. H. Müller, A. Spannenberg, H.-J. Drexler, U. Rosenthal, M. H. Al-Hazmi, K. E. Al-Eidan, A. Wöhl, W. Müller, Organometallics 2011, 30, 2364-2370. Heterobimetallic Al−Cl−Cr Intermediates with Relevance to the Selective Catalytic Ethene Trimerization Systems Consisting of CrCl3(THF)3, the Aminophosphorus Ligands Ph2PN(R)P(Ph)N(R)H, and Triethylaluminum.
241.M. Kessler, S. Hansen, D. Hollmann, M. Klahn, T. Beweries, A. Spannenberg, A. Brückner, U. Rosenthal, Eur. J. Inorg. Chem. 2011, 627-631. Synthesis of Cp*2Ti(OTf) and Its Reaction with Water.
240.B. H. Müller, N. Peulecke, S. Peitz, B. R. Aluri, U. Rosenthal, M. H. Al-Hazmi, F. M. Mosa, A. Wöhl, W. Müller, Chem. Eur. J. 2011, 17, 6935-6938. Activity Enhancement of a Catalyst System for Selective Ethene Trimerization to 1-Hexene by Modification of the Chromium to Chloride to Aluminium Ratio.
239.V. V. Burlakov, K. Kaleta, T. Beweries, P. Arndt, W. Baumann, A. Spannenberg, V. B. Shur, U. Rosenthal, Organometallics 2011, 30, 1157-1161. Reactions of Five-membered Metallacyclocumulenes Cp2M(η4-t-Bu-C4-t-Bu) (M = Ti, Zr) with Diisobutylaluminum Hydride.
238.

K. Kaleta, P. Arndt, A. Spannenberg, U. Rosenthal, Inorg. Chem. Acta. 2011, 370, 187-190. Unusual Bond Activation Processes in the Reaction of Group 4 Cyclopentadienyl Alkyne Complexes with Azobenzene.

237.H. J. Breunig, O. Moldovan, M. Nema, U. Rosenthal, C.I. Rat and R.A. Varga, J. Organomet. Chem. 2011, 696, 523-526. Formation of [Cp2TiSbMe2]2, [Cp2TiSb(SiMe3)2]2 and [Cp2TiCl]2·2Mes4Sb2.
236.N. Peulecke, S. Peitz, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta  Crystallographica Section E, 2010, E66, m1495. [2,2-Bis(diphenylphosphanyl)propane-κ2P,P’]tetracarbonylchromium(0) dichloromethane monosolvate.
235.N. Peulecke, S. Peitz, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta  Crystallographica Section E, 2010, E66, m1494. Bis(diphenylphosphanyl)dimethylsilane-κ2P,P’]tetracarbonylchromium(0).
234.O. Theilmann, M. Ruhmann, A. Villinger, A. Schulz, W. W. Seidel, K. Kaleta, T. Beweries, P. Arndt, U. Rosenthal, Angew. Chem. 2010, 122, 9469-9473; Angew. Chem, Int. Ed. 2010, 49, 9282-9285. [Cp2TiIII(NCy)2CTiIIICp2]: A transiente Titanocene Carbene Complex?
233.M. Keßler, A. Spannenberg, U. Rosenthal, Acta Crystallographica Section E, 2010, E66, m1400. Iodido(η5-pentamethylcyclopentadienyl)titanium(III).
232.K. Kaleta, P. Arndt, A. Spannenberg, U. Rosenthal, Acta Crystallographica Section E, 2010, E66, m1180. (tert-Butylimido)bis(η5-cyclopentadienyl)pyridine-zirconium(IV) hemisolvate.
231.VIP mit COVER: S. Peitz, N. Peulecke, B. R. Aluri, B. H. Müller, A. Spannenberg, U. Rosenthal, M. H. Al-Hazmi, F. M. Mosa, A. Wöhl, W. Müller, Chem. Eur. J. 2010, 16, 12127-12132. Activation and Deactivation by Temperature: Behavior of Ph2PN(iPr)P(Ph)N(iPr)H in the Presence of Alkylaluminum Compounds Relevant to Catalytic Selective Ethene Trimerization.
230.S. Peitz, N. Peulecke, B. R. Aluri, B. H. Müller, A. Spannenberg, U. Rosenthal, M. H. Al-Hazmi, F. M. Mosa, A. Wöhl, W. Müller, Organometallics. 2010, 29, 5263-5268. Metalation and Transmetalation Studies on Ph2PN(iPr)P(Ph)N(iPr))H for Selective Ethene Trimerization to 1-Hexene.
229.U. Rosenthal, S. Peitz, S. Hansen, B. R. Aluri, N. Peulecke, B. H. Müller, A. Wöhl, W. Müller, M. H. Al-Hazmi, F. M. Mosa, Chem. Eur. J. 2010, 7670-7676. Alternative Mechanistic Concept for Homogeneous Selective Ethylene Oligomerization of Chromium-based Catalysts: Binuclear Metallacycles as reason for 1-octene selectivity?
228.B. R. Aluri, N. Peulecke, S. Peitz, A. Spannenberg, B. H. Müller, S. Schulz, D. Heller, M. H. Al-Hazmi, F. M. Mosa, A. Wöhl, W. Müller, U. Rosenthal, Dalton Trans. 2010, 7911-7920. Coordination Chemistry of new selective ethylene trimerization ligand Ph2PN(iPr)P(Ph)NH(R) (R = iPr, Et) and preliminary tests in catalysis.
227.K. Kaleta, P. Arndt, T. Beweries, A. Spannenberg, O. Theilmann, U.  Rosenthal, Organometallics 2010, 29, 2604-2609. Reactions of Group 4 Metallocene Alkyne complexes with Diazobenzene – Formation of Diazametallacyclopropanes vs. N=N Bond Activation.
226.Ch. Fischer, T. Beweries, A. Preetz, H.-J. Drexler, W. Baumann, S. Peitz, U. Rosenthal, D. Heller, Catalysis Today 2010, 155, 282-288. Kinetic and mechanistic investigations in homogeneous catalysis using operando UV/vis spectroscopy.
225.W. Müller, A. Wöhl, S. Peitz, N. Peulecke, B. R. Aluri, B. H. Müller, D. Heller, U. Rosenthal, M. H. Al-Hazmi, F. M. Mosa, ChemCatChem. 2010, 2, 1130-1142. A kinetic model for the selective ethene-trimerization to 1-hexene, using a novel chromium catalyst system.
224.O. Theilmann, M. Ruhmann, A. Schulz, A. Villinger, U. Rosenthal, Inorg. Chem. Comm. 2010, 13, 837-839. Reaction of the Titanocene Alkyne Complex Cp2Ti(η2-Me3SiC2SiMe3) with Selenium Dioxide: Preparation and Characterization of a Novel Tetranuclear Titanium Complex with Selenium and Oxo bridges.
223.N. Peulecke, B. H. Müller, S. Peitz, B. R. Aluri, U. Rosenthal, A. Wöhl, W.
Müller, M. H. Al-Hazmi, F. M. Mosa, ChemCatChem 2010, 2, 1079-1081.
Immobilized new Chromium Catalyst System for Selective Ethene Trimerization to 1-Hexene with a PNP-NH Ligand.
222.A. Wöhl, W. Müller, S. Peitz, N. Peulecke, B. R. Aluri, B. H. Müller, D. Heller, U. Rosenthal, M. H. Al-Hazmi, F. M. Mosa, Chem. Eur. J. 2010, 16, 7833-7842. Influence of process parameters on the reaction kinetics of the chromium-catalyzed trimerization of ethylene.
221.V. V. Burlakov, V. S. Bogdanov, K. A.  Lissenko, L. I. Strunkina, М. Х. Minaschewa, B. N. Strunin, U. Rosenthal, V. B. Schur, Izv. Akad. Nauk, Ser. Khim. (Russ. Chem. Bull), 2010, 59, 668-670. Formation of the five-membered zirconacyclocumulene Cp2Zr(η4-t-Bu-C4-t-Bu) and the binuclear zirconocene butatrienyl complex Cp2(t-Bu)Zr(t-BuC4t-Bu)ZrCp2(t-Bu) in the reaction of the Negishi reagent with 1,4-di(tert-butyl)butadiene.
220.V. V. Burlakov, T. Beweries, K. Kaleta, V. S. Bogdanov, P. Arndt, W. Baumann, A. Spannenberg, V. B. Shur, U. Rosenthal, Organometallics 2010, 29, 2367-2371. Reactions of the Five-membered Hafnacyclocumulene Cp2Hf(η4-t-Bu-C4-t-Bu) with the Lewis Acids Tris(pentafluorophenyl)borane and Diisobutylaluminum hydride.
219.M. Klahn, A. Spannenberg, U. Rosenthal, Z. Kristallogr. NCS 2010, 225, 262-264. Crystal structure of 1-bis(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)cyclopentadienyl)-1-trimethylphosphine-2,3-bis(trimethylsilyl)-1-hafnacycloprop-2-ene - hexane (1:0.5), (HfC8H18Si2) (C15H22)2(PC3H9) · 0.5C6H14.
218.T. Beweries, A. Spannenberg, U. Rosenthal, Z. Kristallogr. NCS 2010, 225, 191-193. Crystal structure of bis(pentamethylcyclopentadienyl)(1-tert-butylisocyanido)-2-trimethylsilyl-3-[(trimethylsilyl)ethynyl]-hafnacyclopropene, (C10H15)2(C5H9N)Hf(C10H18Si2).
217.T. Beweries, A. Spannenberg, U. Rosenthal, Z. Kristallogr. NCS 2010, 225, 188-190. Crystal structure of bis(pentamethylcyclopentadienyl)-(4,4'-di-tert-butylbipyridyl)hafnium(IV)—hexane (1:0.5), Hf(C10H15)2(C18H24N2) · 0.5C6H14.
216.S. Peitz, N. Peulecke, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Crystallographica Section E 2010, E66(3), m296-m297. Bis[N,N'-bis(2,6-diisopropylphenyl)ethene-1,2-diamido]-1,4(2);1:2 4N:N;3:4 4N:N-bis(diethyl ether)-1 O,4 O-di- hydrido-2:3 4H:H-2,3-dichromium(II)-1,4-dilithium(I) pentane hemisolvate.
215.M. Lamač, A. Spannenberg, H. Jiao, S. Hansen, W. Baumann, P. Arndt, U. Rosenthal, Angew. Chem. 2010, 122, 2999-3002- Angew. Chem., Int. Ed. 2010, 49, 2937-2940; Formation of 1-Zircona-2,5-disilacyclopent-3-yne: Coordination of 1,4-Disilabutatriene to Zirconocene?
214.M. Lamač, A. Spannenberg, W. Baumann, H. Jiao, Ch. Fischer, S. Hansen, P. Arndt, U. Rosenthal, J. Am. Chem. Soc. 2010, 132, 4369-4380. Si-H Bond Activation of Alkynylsilanes by Group 4 Metallocene Complexes.
213.S. Peitz, N. Peulecke, B. R. Aluri, S. Hansen, B. H. Müller, A. Spannenberg, U. Rosenthal, M. H. Al-Hazmi, F. M. Mosa, A. Wöhl, W. Müller, Eur. J. Inorg. Chem. 2010, 1167-1171. A Selective Chromium Catalyst System for the Trimerization of Ethene and its Coordination Chemistry.
212.B. R. Aluri, N. Peulecke, B. H. Müller, S. Peitz, A. Spannenberg, M. Hapke, U. Rosenthal, Organometallics 2010, 29, 226-231. Synthesis, Coordination Chemistry, and Catalysis of the First Bis(diphenylphosphino)-1,2-diphenylhydrazine, Ph2PN(Ph)N(Ph)PPh2.
211.E. D. Jemmis, S. Roy, V. V. Burlakov, H. Jiao, M. Klahn, S. Hansen, U. Rosenthal, Organometallics 2010, 29, 76-81. Are Metallocene-Acetylene (M = Ti, Zr, Hf) Complexes Aromatic Metallacyclopropenes?
210.S. Peitz, N. Peulecke, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Crystallographica Section E 2009 E65, m1574; Bis[[N,N´-bis(2,6-diisopropylphenyl)ethane-1,2-diimine]1k2N,N’;2k2N,N’-tri-u-trichlorido-1:2k6Cl:Cl-chlorido-1kCl-tetrahydrofuran-2kO-dichromium(II) dichlormethane 4.5-solvate.
209.S. Peitz, N. Peulecke, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Crystallographica Section E, 2009 E65, m1336. Diacetonitril[N,N´-bis(2,6-diisopropylphenyl)ethane-1,2-diimine]dichlorochromium(II) acetonitrile solvate.
208.M. Lamač, A. Spannenberg, P. Arndt, U. Rosenthal, Acta Crystallographica Section E 2009, E65, m1481. [1-Dimethylsilyl-2-phenyl-3-(tetramethylcyclopentadienyl)-prop-1-en-1-yl](pentamethylcyclopentadienyl)titanium(III).
207.H. J. Breunig, E. Lork, O. Moldovan, C. I. Ra, U. Rosenthal, C. Silvestru, Dalton Trans., 2009, 5065–5067. Polynuclear titanocene complexes with antimony ligands: [(Cp2Ti)2(SbR2)2] (R = Et), [(Cp2Ti)3(SbR)3Sb] [R = 2-(Me2NCH2)C6H4] and [(Cp2Ti)5(SbR)2Sb7] (R = Me3SiCH2).
206.M. Hapke, A. Wöhl, S. Peitz, A. Spannenberg, U. Rosenthal, Acta Cryst. Sect. E 2009, E65, m357. trans-Di-acetato-[N,N-bis(diphenylphosphino)aniline]bis-[chloride-molybdenum(II)] (Mo-Mo)-dichloromethane-tetrahydrofuran (1/0.3/1.7).
205.V. V. Burlakov, T. Beweries, V. S. Bogdanov, P. Arndt, W. Baumann, A. Spannenberg, K. A. Lyssenko, V. B. Shur, U. Rosenthal, Organometallics 2009, 28, 2864-2870. Synthesis and Isolation of Di-n-butylhafnocene and Its Application as a Versatile Starting Material for the Synthesis of Hafnacycles.
204.T. Beweries, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Eur. J. Inorg. Chem. 2009, 1456-1459. Synthesis of Hafnacyclopentanes from Hafnocene Alkyne Complexes: Influence of Styrene Substituents on the C-C Coupling Regioselectivity.
203.B. R. Aluri, S. Peitz, A. Wöhl, N. Peulecke, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Cryst. Sect. E, 2009, E65, O404. 1,1,2,2-Tetraphenyl-1λ5-diphosphane 1-sulfide.
202.M. Hapke, A. Wöhl, S. Peitz, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Cryst. Sect. E 2009, E65, m252. [N,N-Bis(diphenylphosphino)isopropylamine]dibromidonickel(II).
201.T. Beweries, C. Fischer, S. Peitz, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, D. Heller, U. Rosenthal, J. Am. Chem. Soc. 2009, 131, 4463-4469. Combination of Spectroscopic Methods: in situ NMR and UV/Vis Measurements to understand the Formation of Group 4 Metallacyclopentanes from the corresponding Metallacyclopropenes.
200.T. Beweries, V. V. Burlakov, U. Rosenthal, A. Spannenberg, Z. Kristallogr. NCS 2009, 93-94. Crystal structure of 1,1-bis(pentamethylcyclopentadienyl)-4,5-bis(trimethylsilyl)-1-hafnafuran-3-one, Hf(C10H15)2(Me3SiC2SiMe3CO2).
199.T. Beweries, V. V. Burlakov, U. Rosenthal, A. Spannenberg, Z. Kristallogr. NCS 2009, 95-97. Crystal structure of rac-[1,2-ethylene-bis(η5-4,5,6,7-tetrahydroindenyl)]-1-hafna-4,5-bis(trimethylsilyl)furan-3-one-tris(pentafluorophenyl)borane,
(C20H24)Hf(Me3SiC2SiMe3CO2)B(C6F5)3.
198.M. Klahn, P. Arndt, V. V. Burlakov, A. Spannenberg, U. Rosenthal, Organometallics 2009, 27, 915-918. Syntheses and Reactions of First Chiral Group 4 Metallocene Alkyne Complexes:(η5-menthyl-C5H4)2M(η2-Me3SiC2SiMe3) M = Ti, Zr.
197.P. Arndt, V. V. Burlakov, A. Spannenberg, M. Klahn, D. Heller, C. Fischer, U. Rosenthal, Inorg. Chem. Comm. 2008, 12, 1452-1454. Reaction of the Titanocene Alkyne Complex Cp2Ti(η2-Me3SiC2SiMe3) with Methanol: Preparation and Characterisation of a Novel Trinuclear Titanium Complex [{Cp2Ti(OMe)}2{Ti(OMe)4}].
196.A. Wöhl, W. Müller, N. Peulecke, B. H. Müller, S. Peitz, U. Rosenthal, J. Mol. Cat. A: Chemical, 2009, 297, 1-8. Reaction Kinetics of Ethene Tetramerization Chromium Catalyst: The unexpected and unusual Formation of odd-numbered 1-Olefins.
195.Book contribution: U. Rosenthal, V. V. Burlakov, P. Arndt, A. Spannenberg, U. Jäger-Fiedler, M. Klahn, M. Hapke, Activating Unreactive Bonds, (Eds. C. Bolm and F. E. Hahn) Wiley-VCH, 2009, 165-182. Reactions of C—F bonds with Titanocene and Zirconocene:From Secondary Interaction via Bond Cleavage to Catalysis.
194.M. Klahn, P. Arndt, A. Spannenberg, A. Gansäuer, U. Rosenthal, Organometallics 2008, 27, 5846-5851. Menthyl Substituted Group 4 Metallocene Dihalides.
193.V. V. Burlakov, V. C. Bogdanow, K. A. Lyssenko, P. V. Petrovskii, T. Beweries, P. Arndt, U. Rosenthal, V. B. Shur, Russ. Chem. Bull. (Russ.) 2008, 57, 1319-1320. First Structural Characterization of a five-membered Hafnacyclocumulene Cp2Hf[η4-t-BuC4-t-Bu).
192.U. Rosenthal, Angew. Chem. 2008, 120, 5196-5199. Angew. Chem., Int. Ed. 2008, 47, 5118-5121. Discovering Chemical Terra Incognita: Unusual Metallacycles and Their Reactions.
191.T. Beweries, V. V. Burlakov, S. Peitz, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2008, 27, 3954-3959. Synthesis and Reactions of Cp*2Hf(η2-Me3SiC2SiMe3) with Water and Carbon Dioxide.
190.U. Rosenthal, GIT Labor.Fachzeitschrift 2008, 4, 394-397. Manche Metalle machen’s möglich!
189.A. Spannenberg, V. V. Burlakov, U. Rosenthal, Crystal structure of η5-1-(tris(pentafluorophenyl)boranylmethyl)-2,3,4,5-tetramethylcyclopentadienyl-η5η1-3,6-di-tert-butyl-9,10,11-trimethyl-bicyclo(6.3.0)undeca-3-en-8,10-dienyl)-titanium, Ti(C50H48BF15), Z. Kristallogr. NCS 2008, 64-66.
188.U. Rosenthal, CHEManager 2008, 4, 7. Manche Metalle machen’s möglich!
187.

M. Schaffrath, A. Schulz, A. Villinger, U. Rosenthal, Organometallics 2008, 27, 1393-1398. Titanocene-mediated formation of phosphorous-phosphorous bonds – a new synthesis for diphosphenes and dichlorodiphosphanes.

186.A. Spannenberg, V. V. Burlakov, U. Rosenthal, Crystal structure of η5-3,6-di-tert-butyl-4-(tris(pentafluorophenyl)boranyl-oxycarbonyl)-5-(η5-tetramethylcyclopentadienyl-methyl-9,10,11-trimethyl-bicyclo(6.3.0)undeca-4-en-8,10-dienyl)-titanium toluene hemisolvate, Ti(C51H47BF15O2)∙0.5C7H8.; Z. Kristallogr. NCS 2008, 61-63.
185.

A. Spannenberg, V. V. Burlakov, U. Rosenthal, Crystal structure of tribromo-(η5-3,6-di-tert-butyl-9,10,11-trimethylbicyclo(6.3.0)undeca-4-en-8,10-dienyl)-titanium, Ti(C22H35)Br3, and tribromo-(η5-4,5-dibromo-3,6-di-tert-butyl-9,10,11-trimethylbicyclo(6.3.0)undeca-8,10-dienyl)-titanium, Ti(C22H35Br2)Br3, Z. Kristallogr. NCS 2008, 57-60.

184.

U. Jäger-Fiedler, M. Klahn, P. Arndt, W. Baumann, A. Spannenberg, V.V.Burlakov, U.Rosenthal, J. Mol. Cat. A: Chem. 2007, 261, 184-189. Room-temperature catalytic hydrodefluorination of pentafluoro-pyridine byzirconocene fluoro complexes and diisobutylaluminumhydride.

183.

T. Beweries, V. V. Burlako, M. A. Bach, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal: Organometallics 2007, 26, 247-249. Complexation of bis(trimethylsilyl)acetylene by decamethylhafnocene to give the hafnacyclopropene Cp2Hf(η2-Me3SiC2SiMe3): An unusually strong metal-alkyne interaction.

182.

T. Beweries, M. A. Bach, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal: Organometallics 2007, 26, 241-244. Synthesis of ansa-Dimethylsilanediyl-dicyclopentadienyl-zirconacyclopent-3-yne, Me2Si(η5-C5H4)2Zr(η4-H2C4H2), and Its Reactions with Ni(0) and B(C6F5)3.

181.

Mit Cover: P. Arndt, V. V. Burlakov, U. Jäger-Fiedler, M. Klahn, A. Spannenberg, W. Baumann, U. Rosenthal: Coll. Czech Chem. Comm. 2007, 72, 475-491. Reactions of Titanocene- and Zirconocene-Bis(trimethylsilyl)acetylene Complexes with Selected Heterocyclic and Aromatic NH and OH Acid Compounds.

180.P. Arndt, V. V. Burlakov, A. Spannenberg, U. Rosenthal, Inorg. Chem. Comm. 2007, 10, 792-794. Synthesis of Decamethyltitanocene alkyne complexes and Molecular structure of the Diphenylacetylene complex Cp*2Ti(h2-PhC2Ph).
179.

M. A. Bach, P. Parameswaran, E. D. Jemmis, U. Rosenthal:

Organometallics 2007, 26, 2149-2156. Bimetallic Complexes of Metallacyclopentynes: cis versus trans and Planarity versus Nonplanarity.
178.Review mit Cover: U. Rosenthal, V. V. Burlakov, M. A. Bach, T. Beweries, Chem. Soc. Rev. 2007, 36, 719-728. Five-Membered Metallacycles of Titanium and Zirconium – Attractive Compounds for Organometallic Chemistry and Catalysis.
177.

M. A. Bach, T. Beweries, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal: Organometallics 2007, 26, 4592-4597. Migratory Insertion of an Isocyanide into 1-Zirconacyclopent-3-ynes.

176.

T. Beweries, U. Jäger-Fiedler, M. A. Bach, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal: Organometallics 2007, 26, 3000-3004. Ring-Opening Reactions of Tetrahydrofuran versus Alkyne Complexation by Group 4 Metallocene Complexes Leading to General Consequences for Synthesis and Reactions of Metallocene Complexes.

175.

H. J. Breunig, T. Borrmann, E. Lork, C. I. Rat, U. Rosenthal, Organometallics 2007, 26, 5364-5368. Synthesis and Structures of Distibine Complexes of Tungsten and Titanium.

174.

T. Beweries, V. V. Burlakov, M. A. Bach, S. Peitz, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, B. Pathak, E. D. Jemmis, Angew. Chem. 2007, 119, 7031-7035. Angew. Chem, Int. Ed. 2007, 46, 6907-6910.

Tandem-Aktivierung von Si-C- und C-H-Bindungen bei Decamethylhafnocen und Bis(trimethylsilyl)acetylen. Angew. Chem. 2007, 119, 7031-7035. Tandem Si-C and C-H Activation for Decamethylhafnocene and Bis(trimethylsilyl)acetylene.
173.

T. Beweries, V. V. Burlakov, S. Peitz, M. A. Bach, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2007, 26, 6827-6831. Reactions of Decamethylhafnocene with 1,3-Butadiynes: Formation of Hafnacyclocumulenes and C−H Activation at Pentamethylcyclopentadienyl Ligands.

172.

M. Klahn, C. Fischer, A. Spannenberg, U. Rosenthal, I. Krossing:

Tetrahedron Lett. 2007, 48, 8900-8903. Hydrodefluorination of non- activated C–F bonds by diisobutyl-aluminiumhydride via the aluminium cation [i-Bu2Al]+.

171.

L. I. Strunkin, M. K. Minacheva, K. A. Lyssenko, P. V. Petrovskii, N. E. Mysova, B. N. Strunin, V. Burlakov, U. Rosenthal, V. B. Shur: Organomet. Chem. 2007, 692, 4321-4326. Electrophilic reactivity of the zwitterionic titanocene monohalides Cp[η5-C5H4B(C6F5)3]TiX (X = Cl, Br): Reactions with water and methanol.

170.

A. Spannenberg, T. Beweries, M. A. Bach, U. Rosenthal: Kristallogr. NCS 2007, 222, 187-188. Crystal structure of m-oxo-bis(s-1,2-bis(trimethylsilyl)vinylhafnocene) benzene solvate, [C2H{Si(CH3)3}2Hf(C5H5)2]2 O · C6H6.

169.

A. Spannenberg, M. A. Bach, T. Beweries, U. Rosenthal: Kristallogr. NCS 2007, 222, 189-191. Crystal structure of 3,3-bis(tert-butyl-cyclopentadienyl)-bicyclo[3.1.0]hex-3-zircona-1(5)-ene-6-nickela-6,6-bis(triphenylphosphine), (C9H13)2 (ZrC4H4)Ni(C18H15P)2.

168.

A. Spannenberg, V. V. Burlakov; P. Arndt, M. Klahn, U. Rosenthal,

Z. Kristallogr. NCS 2007, 222,192-194. Crystal structure of bis(η5-cyclopentadienyl)-pyrrolide-titanium(III), Ti(C10H15)2(C4H4N).

167.

P. Arndt, U. Jäger-Fiedler, M. Klahn, W. Baumann, A. Spannenberg, V. V. Burlakov, U. Rosenthal, Angew. Chem. 2006, 118, 4301-4304. Angew. Chem, Int. Ed. 2006, 45, 4195-4198. Formation of Zirconocene Fluoro Complexes: No Deactivation of Olefins by the Contact-Ion-Pair Catalysts [Cp’2ZrR]+[RB(C6F5)3]-.

166.

M. Penno, A. Zapf, U. Rosenthal, Chem. Ing. Techn. 2006, 78, 817-824. Neues Zentrum für Angewandte Katalyseforschung: Institute aus Berlin und Rostock fusionieren zum Leibniz-Institut für Katalyse e.V. an der Universität Rostock.

165.

L. I. Strunkina, M. Kh. Minacheva, K. A. Lyssenko, P. V. Petrovskii, V. V. Burlakov, U. Rosenthal, V- B. Shur, Russ. Chem. Bull. Int. Ed. 2006, 55, 174-176. Protolytic B-C6F5 bond cleavage in the zwitterionic titanocene monochloride Cp[η5-C5H4B(C6F5)3]TiCl with water to form titanocene chloride hydroxide complex Cp[η5-C5H4B(C6F5)2]TiCl(μ-OH).

164.

V. V. Burlakov, M. A. Bach, M. Klahn, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Macromol. Symp. 2006, 236, 48-53. Activation of Metallacyclopropenes, five-membered Metallacyclocumulenes and Metallacyclopentynes of Zirconium with i-Bu2AlH.

163.

K. A. Rufanov, B. H. Müller, A. Spannenberg, U. Rosenthal, New J. Chem. 2006, 30, 29-31. Synthesis and molecular structures of the first phosphoranylidene complexes of the rare earth metal.

162.

V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2006, 25, 1317-1320. Simple Functionalizations by Reactions of Decamethylzirconocene Complexes with Carbon Dioxide.

161.

V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2006, 25, 519-522. Simple Alumination Reactions of Pentametylcyclopentadienyl Ligands in the Decamethylzirconocene-Bis(trimethylsilyl)acetylene Complex Cp*2Zr(-(η2-Me3SiC2SiMe3).

160.

A. Spannenberg, B. H. Müller, U. Rosenthal, Z. Kristallogr. 2005, 220, 581-584. Crystal structure of tris[(diphenylphosphino)methylene)-diphenylphosphoranyl-methyl]yttrium diethyl ether monosulvate, [Y{P(C6H5)2CHP(C6H5)2CH2}3]∙(C2H5)2O.

159.

A. Spannenberg, U. Jäger-Fiedler, P. Arndt, U. Rosenthal, Z. Krist. 2005, 220, 253-254. Crystal Structure of rac-1,2-ethylene-1,1’-bis(η5-tetrahydroindenyl)-chloro-(η2-N,C-3,4,5,6-tetrafluoro-pyridyl)-zirconium(IV).

158.

M. A. Bach, T. Beweries, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal,  W. Bonrath, Organometallics 2005, 24, 5916-5918. Reactions of 1-Titana- und 1-Zirconacyclopent-3-ynes with Tris(pentafluorophenyl)borane.

157.

M. A. Bach, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2005, 24, 3047-3052. Nickel(0) Complexes of 1-Zirconacyclopent-3-yne.

156.

U. Jäger-Fiedler, P. Arndt, W. Baumann, V. V. Burlakov, A. Spannenberg, U. Rosenthal, Eur. J. Inorg. Chem. 2005, 2842-2849. Reactions of Zirconocene Bis(trimethylsilyl)acetylene Complexes with Fluorinated Pyridines: C—H versus C—F Bond Activation.

155.

Review: U. Rosenthal, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, Organometallics 2005, 24, 456-471. Five-Membered Titana-and Zirconacyclocumulenes - Stable 1-Metallacyclopenta-2,3,4-trienes.

154.

Book contribution: U. Rosenthal in Acetylene Chemistry - Chemistry, Biology, and Material Science (Eds.: F. Diederich, P. Stang and R. R. Tykwinski) Wiley-VCH, 2004, 139-171. Transition Metal Acetylides.

153.

Micro-Review: U. Rosenthal, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, Eur. J. Inorg. Chem. 2004, 22, 4739-4750. Titanocene and Zirconocene Complexes of Bis(trimethylsilyl)acetylene: Recent Chemistry and Reactions with Lewis Acids.

152.

M. Horacek, I. Cisarova, J. Kubista, A. Spannenberg, K. Dallmann, U. Rosenthal, K. Mach, J. Organomet. Chem. 2004, 689, 4592-4600. Titanocene-1,4,6-tris(trimethylsilyl)hex-3-ene-1,5-diyne-3-yl Complexes - Crystal Structures and their retro Reactions.

151.

V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2004, 23, 5188-5192. Reactions of Five-Membered Zirconacyclocumulenes with Tris(pentafluorophenyl)borane:  Carbon Carbon Double Bond Cleavage and Formation of Novel Zwitterionic Complexes.

150.

V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2004, 23, 4160-4165. Reactions of Five-Membered Zirconacyclocumulenes with Diisobutylaluminum.

149.

Mini-Review: U. Rosenthal, Angew. Chem. 2004, 116, 3972-3977. Angew. Chem., Int. Ed. 2004, 43, 3882-3887;. Stabile Cyclopentine- Metalle machen's möglich!?

148.

A. Spannenberg, P. Arndt, W. Baumann, V. V. Burlakov, U. Rosenthal, S. Becke, T. Weiß, Organometallics 2004, 23, 4792-4795. Reactions of Zirconocene 2-Vinylpyridine Complexes with Diisobutylaluminum Hydride and Fluoride.

147.

A. Spannenberg, P. Arndt, W. Baumann, V. V. Burlakov, U. Rosenthal, S. Becke, T. Weiß, Organometallics 2004, 23, 3819-3825. Novel of Zirconocene Difluoride and Alkyl Mononofluoride Complexes.

146.

V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, P. Parameswaran, E. D. Jemmis, Chem. Commun. 2004, 2074-2075. Reduction of 1,4-Dichloro-but-2-yne by Titanocene to the 1,2,3-Butatriene. Formation of the 1-Titana-cyclo-pent-3-yne and the 2,5-Dititana-bicyclo[2.2.0]hex-1(4)-ene.

145.

E. D. Jemmis, A. K. Phukan, H. Jiao, U. Rosenthal, Organometallics 2003, 22, 4958-4965. Structure and Neutral Homoaromaticity of Metallacyclopentene, -pentadiene, -pentyne and -pentatriene: A Density Functinal Study.

144.

A. Spannenberg, P. Arndt, W. Baumann, U. Rosenthal, J. Organomet. Chem. 2003, 683, 261-266. The Molecular Structure of Cr[(CH2)2PMe2]3: Dimethylphosphonium-bis-methylide Chromium Compounds as Inner-Phosphonium-alkyl-ate- or 2-Phospha-allyl-Complexes?

143.

U. Rosenthal, Angew. Chem. 2003, 115, 1838-1842. Angew. Chem. Int. Ed. Engl. 2003, 42, 1794-1798. "Anziehen" von "nacktem" Acetylid mit Metallkomplexen - Wie und warum macht man das?

142.

P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, V. V. Burlakov, V. B. Shur, Angew. Chem. 2003, 115, 1455-1458. Angew. Chem. Int. Ed. Engl. 2003, 42, 1414-1418. Reaktionen von Titan- und Zirconiumkomplexen des Bis(trimethylsilyl)acetylens mit Tris(pentafluorophenyl)boran: ein Titan(III)-Komplex eines Alkinylboranats.

141.

Review: U. Rosenthal, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, Organometallics 2003, 22, 884-900. The Titanocene Complex of Bis(trimethylsilyl)acetylene: Synthesis, Structure, and Chemistry.

140.

Review: U. Rosenthal, P. Arndt, W. Baumann, V. V. Burlakov, A. Spannenberg, J. Organomet. Chem. 2003, 670, 84-96. Titanocene and zirconocene σ-alkynyl complexes in C-C single bond coupling and cleavage reactions.

139.

L. I. Strunkina, M. Kh. Minachova, K. A. Lisenko, O. I. Chaustova, V. V. Burlakov, U. Rosenthal, V. B. Shur, Izv. Akad. Nauk. Ser. Khim. 2003, 737-738. Russ. Chem. Bull. 2003, 52, 773-774. Synthesis of zwitterionic titanocene-mono-chlorides Cp[η5-C5H4B(C6F5)3]TiCl, containing the tris(pentafluorophenylo)borane group at the η5-cyclopentadienyl ring.

138.

V. V. Burlakov, A. V. Letov, P. Arndt, W. Baumann, A. Spannenberg, Ch. Fischer, L. I. Strunkina, M. Kh. Minachova, Ya. S. Vygodskii, U. Rosenthal, V. B. Shur; J. Mol. Cat. 2003, 200, 63-67. Zwitterionic Titanoxanes {Cp[η5-C5H4B(C6F5)3]Ti}2O and {(η5-iPrC5H4)[η5-{1,3-iPrC5H3B(C6F5)3}]Ti}2O as Catalysts for Cationic Ring-Оpening Polymerization.

137.

A. Spannenberg, V. V. Burlakov, P. Arndt, W. Baumann, V. B. Shur, U. Rosenthal, Z. Kristallogr. 2002, 217, 546-548. Crystal Structure of [1,2-ethylene-1,1’-bis(η5-tetrahydroindenyl)] [hydroxytris(pentafluorophenyl) borato]titanium(III), C38H24BF15OTi.

136.

Book contribution: U. Rosenthal, V. V. Burlakov in Titanium and Zirconium in Organic Synthesis, (Ed.: I. Marek) Wiley-VCH, 2002, 355-390. Organometallic Chemistry of Titanocene and Zirconocene Complexes with Bis(trimethylsily)acetylene as the Basis for Applications in Organic Synthesis.

135.

H. Sun, V. V. Burlakov, A. Spannenberg, W. Baumann, P. Arndt, U. Rosenthal, Organometallics. 2002, 21, 3360-3366. Reactions of Zirconocene Alkyne Complexes with Polar Functionalized Olefins.

134.

H. Sun, A. Spannenberg, V. V. Burlakov, W. Baumann, P. Arndt, U. Rosenthal, Z. Kristallogr. 2002, 217, 241-243. Crystal structure of dimeric bis(tetrahydroindenyl)-2-trimethylsilyl-3-trimetylsiloxacarbonyl-zirconafuran-4-one, C56H80O8Si4Zr2.

133.

A. Spannenberg, K. Dallmann, V. V. Burlakov, U. Rosenthal, Z. Kristallogr. 2002, 217, 237-238. Crystal structure of bis(η5-pentamethylcyclopentadienyl)(μ3-(oxy-methylidin)-cyclo-(tricarbonyl-cobalt)(monocarbonylcobalt)-(μ22-3-trimethylpropinyl)titan, C31H39Co2O5Ti.

132.

A. Spannenberg, K. Dallmann, V. V. Burlakov, U. Rosenthal, Z. Kristallogr. 2002, 217, 239-240. Crystal structure of bis(η5-pentamethylcyclopentadienyl)[μ3-(η2-3-trimethyl-propinylcarboxylato)-bis(tricarbonyl-cobalt)-titan], C33H39Co2O8Ti.

131.

A. Spannenberg, W. Baumann, U. Rosenthal, Organometallics 2002, 21, 1512-1514. Five-Membered Titanacyclocumulenes that Contain Linked Amido-Cyclopentadienyl Ligands.

130.

H. Sun, V. V. Burlakov, A. Spannenberg, W. Baumann, P. Arndt, U. Rosenthal, Organometallics. 2001, 20, 5472-5477. Synthesis and Structural Investigation of Stable Zirconacyclopentanes Which bear Additional Functional Groups.

129.

A. Spannenberg, V. V. Burlakov, U. Rosenthal, Z. Kristallogr. 2001, 216, 616-618. Crystal structure of [2,2-Bis(η5-cyclopentadienyl)-bis(η,η1: η2-2-trimethylsilyl-ethinyl)titanium(IV) lithium] [2,2-Bis(η5-cyclopentadienyl)-oxo titanium(III) ½ tetrahydrofurane (C50H78LiOSi2Ti2 ½ C4H8O).

128.

A. Spannenberg, F. G. Kirchbauer, V. V. Burlakov, U. Rosenthal, Z. Kristallogr. 2001, 216, 619-620. Crystal structure of Bis(η5-cyclopentadienyl)(η,η12-2-trimethylsilyl-ethinyl)(chloro)-titanium(III) (C20H28Cl2Si2Ti2).

127.

P. Arndt, A. Spannenberg, W. Baumann, S. Becke, U. Rosenthal, Eur. J. Inorg. Chem. 2001, 2885-2890. Bimetallic Titanocene or Zirconocene/Aluminium Complexes as Active Catalysts in Lactone Polymerizations Reactions.

126.

F. G. Kirchbauer, P.-M. Pellny, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2001, 20, 5289-5296. Synthesis and Carbon Dioxide Reactions of Mono-σ-Alkynyl Titanocene(III) Complexes Cp*2Ti(C≡CR), R = Me, tBu, and the Corresponding ate Complexes [Cp*2Ti(C≡CR)2Li(THF)n], R = SiMe3, tBu, Ph.

125.

V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, A. V. Letov, K. A. Lyssenko, A. A. Korlyukov, L. I. Strunkina, M. Kh. Minacheva, V. B. Shur, Organometallics. 2001, 20, 4072-4079. Synthesis and X-Ray Crystal Structure Determination of New Zwitterionic Complexes of Titanocene.

124.

E.-D. Jemmis, A. K. Phukan, U. Rosenthal, J. Organomet. Chem. 2001, 635, 204-211. Bonding and Cycloaddition Reactions of Metallacyclocumulenes (M = Ti, Zr and Ni): A Theoretical Study.

123.

R. Choukroun, B. Donnadieu, C. Lorber, P.-M. Pellny, W. Baumann, U. Rosenthal, Chem. Eur. J. 2000, 6, 4505-4509. Cp2V Migration along an Octatetrayne Chain: From the Monometallic Complex Cp2V(3-4η-tBuC≡C-C2-C≡CC≡CtBu) to the Dimetallic Complex (Cp2V)2(1-2η:7-8η-tBu-C2-C≡CC≡C-C2-tBu).

122.

A. Spannenberg, W. Baumann, U. Rosenthal, Organometallics 2000, 19, 3991-3993. Palladium(II) Complexes of alpha-Stabilized Phosphorus Ylides.

121.

P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, J. Am. Chem. Soc. 2000, 120, 6317-6318. Reactions of Hexatriynes with Permethyltitanocene and -zirconocene Complexes: First NMR Observation of a Metallocene Sliding along a Polyyne Chain.

120.

W. Baumann, P.-M. Pellny, U. Rosenthal, Magn. Reson. Chem. 2000, 38, 515-519. Dynamic NMR study of a 1,3-diyne bridged dinuclear bis(cyclopentadienyl)titanium complex: understanding the C-C single bond metathesis reaction.

119.

P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, M. Horacek, P. Stepnicka, K. Mach, U. Rosenthal, Organometallics 2000, 19, 2816-2819. Facile Functionalizations of Permethyltitanocene Dichloride to Chiral Permethyltitanocene Complexes.

118.

P.-M. Pellny, N. Peulecke, V. V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2000, 19, 1198-1200. Reactions of Tetraalkynylsilanes (RC≡C)4Si, R = Ph, tBu, SiMe3, with Titanocene and Zirconocene.

117.

Review: U. Rosenthal, P.-M. Pellny, F. G. Kirchbauer, V. V. Burlakov, Acc. Chem. Res. 2000, 33, 119-129. What do Titano- and Zirconocenes do with Diynes and Polyynes ?

116.

V. V. Burlakov, S. I. Troyanov, A. V. Letov, E. I. Mysov, G. G. Furin, U. Rosenthal, V. B. Shur, J. Organomet. Chem. 2000, 598, 243-247. Interaction of Bis(trimethylsilyl)acetylene Complex of Titanocene with Tris(perfluorphenyl)borane. Synthesis and Structure of a New Type of a Zwitterionic Metallocene (η5- C5Me5){η5-[C5Me4B(C6F5)3)]}Ti.

115.

W. Barzyk, K. Lunkenheimer, P. Waszynski, A. Pomianowski, U. Rosenthal, Progr. Coll. & Pol. Science. 2000, 116, 107-112. Ideal (Langmuir-type) surface and electric properties of tert-isopropylphosphine oxide at the air/water interface.

114.

J. C. Earnshaw, M. W. D. Grattan, K. Lunkenheimer, U. Rosenthal, J. Phys. Chem. B. 2000, 104, 2709-2713. The Effect of Inhibition of Molecular Reorientation and the Resulting Consequences for the Dilatational Elastic Modulus.

113.

A. Spannenberg, T. Zippel, and U. Rosenthal, Z. Krist. 2000, 215, 365-366. Crystal Structure of Bis(cyclopentadienyl)titanium-N,N-bis(cyclohexyl)diazabuta-1,3-diene.

112.

Spannenberg, T. Zippel, V. V. Burlakov, U. Rosenthal, Z. Krist. 2000, 215, 367-368. Crystal Structure of Di(bis(cyclopentadienyl)titanium)carbonate.

111.

A. Spannenberg, W. Baumann, U. Rosenthal, Appl. Organomet. Chem. 2000, 14, 611-615. Early Transition Metal Complexes of  α-Keto-Stabilized Phosphorous Ylides.

110.

V. V. Burlakov, P.-M. Pellny, P. Arndt, W. Baumann, A. Spannenberg, V. B. Shur, U. Rosenthal, J. Chem. Soc., Chem. Commun. 2000, 241-242. Reactions of Permethylmetallocene Alkyne Complexes of Titanium and Zirconium with Tris(perfluorphenyl)borane.

109.

G. Kirchbauer, P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Chem. Eur. J. 2000, 6, 81-94. Different C-C-Coupling reactions of Permethylzirconocene and -titanocene with Disubstituted 1,3-Butadiynes.

108.

M. Horacek, P. Stepnicka, R. Gyepes, I. Cisarova, M. Polasek, K. Mach, P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, J. Am. Chem. Soc. 1999, 121, 10638-10639. Novel Addition Reactions of 2,2,7,7-Tetramethyl-3,5-octadiene to the Methyl Groups of a η5-Pentamethyl-cyclopentadienyl Ligand.

107.

P.-M. Pellny, F. G. Kirchbauer, V. V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, J. Am. Chem. Soc. 1999, 121, 8313-8323. Reactivity of Permethylzirconocene and -titanocene toward 1,3-Butadiynes: η4- vs η2-Complexation or C-C-Coupling with the Permethyltitanocene.

106.

P.-M. Pellny, F. G. Kirchbauer, V. V. Burlakov, A. Spannenberg, K. Mach, U. Rosenthal, J. Chem. Soc., Chem. Commun. 1999, 2505 - 2506. Unusual Formation of a Hex-3-ene-1,5-diyne-3-yl Ligand from a 1,3-Butadiyne in the Cp*2TiCl2-/Magnesium System.

105.

P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Organometallics 1999, 18, 2906-2909. Novel Ti6-, Zr3-, and Zr6-Complexes from Branched Polyynes and Titanocene as well as Zirconocene.

104.

P.-M. Pellny, V. V. Burlakov, W. Baumann, A. Spannenberg, U. Rosenthal, Z. Anorg. Allg. Chem. 1999, 625, 910-918. The Influence of Ligands Cp*5-C5Me5) and Cp (η5-C5H5) on the Preparation, Stability and Reactivity of Titanocene- and Zirconocene Complexes: Reactions of the bis(trimethylsilyl)-acetylene Permethylmetallocene Complexes (η5-C5Me5)2M(η2-Me3SiC2SiMe3), M = Ti, Zr, with H2O and CO2.

103.

P.-M. Pellny, V. V. Burlakov, N. Peulecke, W. Baumann, A. Spannenberg, R. Kempe, V. Francke, U. Rosenthal, J. Organomet. Chem. 1999, 578, 125-132. Dimerization of Titanacyclocumulenes to Titanium substituted Radialenes: Synthesis, Stability, and Reactions of Five-Membered Titanacyclocumulenes with a Coupling of Two 1,4-Diphenyl-1,3-butadiyne between Two Titanocene Molecules to Radialene-Like Fused Titanacyclopentadiene Compounds.

102.

A. Lunzer, C. Marschner, B. Winkler, N. Peulecke, W. Baumann, U. Rosenthal, Monatsh. Chem. 1999, 130, 215-219. Group IV Metallocene Bis(trimethylsilyl)acetylene Complexes as Catalysts in the Dehydrocoupling Polymerization of 1,2-Disubstituted Hydrosilanes.

101.

R. Kempe, A. Spannenberg, N. Peulecke, U. Rosenthal, Z. Krist. 1998, 213, 789-790. Crystal Structure of 2,2-bis(η5-2,4-cyclopentadiene-1-yl)-2,5-Bis(dimethylsilyl)-3,4-bis(phenyl)-titana-cyclopentadiene.

100.

R. Kempe, A. Spannenberg, N. Peulecke, U. Rosenthal, Z. Krist. 1998, 213, 793-794. Crystal Structure of dimeric 2,2-bis(η5-2,4-cyclopentadiene-1-yl)-2-zirconium-3-trimethylsilyl-4-dimethyl-silyl-furan-5-on.

99.

R. Kempe, A. Spannenberg, C. Lefeber, T. Zippel, U. Rosenthal, Z. Krist. 1998, 213, 791-792. Crystal Structure of 1-Phenyl-2,2-bis((η5-2,4-cyclopentadiene-1-yl)-2-(pyridin)-2-zircona-3-phenyl-3-methyl-aziridine.

98.

T. Zippel, P. Arndt, A. Ohff, A. Spannenberg, R. Kempe, U. Rosenthal, Organometallics 1998, 17, 4429-4437. Reactions of 1,4- and 2,3-Diazadienes with Titanocene and Zirconocene Complexes of Bis(trimethylsilyl)acetylene: Acetylene Coupling or -Substitution including Subsequent C-H Activation, C-C Coupling, and N-N Cleavage to Heterobimetallic Complexes.

97.

D. Thomas, N. Peulecke, V.V. Burlakov, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Eur. J. Inorg. Chem. 1998, 1495-1502. Untypical Regioselectivity of Carbon Dioxide Coupling with Titanocene Complexes of Phenyl(trimethylsilyl)acetylene by using meso-[1,2-Ethylene-1,1’-bis(η5-tetrahydroindenyl)] ligand system.

96.

D. Thomas, P. Arndt, N. Peulecke, A. Spannenberg, R. Kempe, U. Rosenthal, Eur. J. Inorg. Chem. 1998, 1351-1357. Reactions of ε-Caprolactone with Zirconocene Alkyne Complexes: Investigations of Elemental Steps in Catalytic Ring Opening Polymerization of Lactones.

95.

A. Tillack, P. Arndt, A. Spannenberg, R. Kempe, T. Zippel, U. Rosenthal, Z. Anorg. Allg. Chem. 1998, 624, 2038-2042. Reaktionen von Cp2Ti(Me3SiC≡CSiMe3) mit O-Trimethylsilylbenzaldoxim unter Bildung eines Nitril- und eines Titana-diazacyclopentan-Komplexes.

94.

N. Peulecke, A. Ohff, P. Kosse, A. Tillack, R. Kempe, A. Spannenberg, W. Baumann, V. V. Burlakov, U. Rosenthal, Chem. Eur. J. 1998, 4, 1852-1861. Si-H-Activation in Titanocene- and Zirconocene Complexes of Alkynylsilanes RC≡CSiMe2H (R = tBu, Ph, SiMe3, SiMe2H): A Model to Understand Catalytic Reactions of Hydrosilanes.

93.

S. Pulst, F. G. Kirchbauer, B. Heller, W. Baumann, U. Rosenthal, Angew. Chem. 1998, 110, 2029-2031. Angew. Chem. Int. Ed. Engl. 1998, 37, 1915-1927; Erste C-C-Einfachbindungs-Metathese in homogener Lösung: Titanocen-vermittelte und photokatalysierte Spaltung und Rekombination disubstituierter Butadiine.

92.

R. Kempe, A. Spannenberg, N. Peulecke, U. Rosenthal, Z. Krist. 1998, 213, 629. Crystal Structure of bis(tetrahydroindenyl)-zirconium-[η2-bis(trimethylsilyl)acetylene]η1-pyridine.

91.

D. Thomas, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Organometallics 1998, 17, 2096-2102. Zirconocene and rac-[1,2-Ethylene-1,1’-bis(η5-tetrahydroindenyl)]zirconium-Complexes of 2-Vinylpyridine - Syntheses, X-ray Crystal Structures, Reactions with H2C=CH2, H2O, HBF4 and CO2.

90.

D. Thomas, N. Peulecke, V. V. Burlakov, B. Heller, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, R. Beckhaus, Z. Anorg. Allg. Chem. 1998, 624, 919-924. Katalysatordesaktivierungen bei der Acetylen-Polymerisation mit Titanocen- bzw. Zirconocen-Komplexen des Bis(trimethylsilyl)acetylen.

89.

A. Ohff, T. Zippel, P. Arndt, A. Spannenberg, R. Kempe, U. Rosenthal, Organometallics 1998, 17, 1649-1651. Reactions of Azines with Titanocene: C-H Activation, C-C Coupling, and N-N Cleavage to Heterobimetallic Complexes.

88.

Tillack, P. Arndt, A. Spannenberg, R. Kempe, U. Rosenthal, Z. Anorg. Allg. Chem. 1998, 624, 737-740. N-O-Bindungsspaltung in O-silylierten Oximen bei der Reaktion mit einem Titanocen-Alkin-Komplex.

87.

R. Kempe, A. Spannenberg, N. Peulecke, U. Rosenthal, Z. Krist. 1998, 213, 423. Crystal Structure of Tetrakis-(tetrahydroindenyl)-μ-oxo-dititanium.

86.

R. Kempe, A. Spannenberg, N. Peulecke, U. Rosenthal, Z. Krist. 1998, 213, 425. Crystal Structure of 1,1-Biscyclopentadienyl-3,4-diphenyl-titanadioxolane.

85.

Book contribution: A. Ohff, S. Pulst, V. V. Burlakov, C. Lefeber, U. Rosenthal, Max-Planck-Gesellschaft, Jahrbuch 1997, Vandenhoeck & Ruprecht, Göttingen 1998, 713-718.

84.

N. Peulecke, W. Baumann, R. Kempe, V.V. Burlakov, U. Rosenthal, Eur. J. Inorg. Chem. 1998, 419-424. Stability of Bridged and Unbridged Titanocene- and Zirconocene-η2-Alkyne Complexes Influence of Metals, Alkyne-Substituents, Cp-Substitution and Additional Ligands.

83.

U. Rosenthal, S. Pulst, R. Kempe, B. Proft, R. Goddard, K. Pörschke, Tetrahedron 1998, 54, 1277-1287. Pyridine-Based Mono(ligand)-nickel(0) Complexes of 1,6-Heptadiene, 1-Phenyl-2-trimethylsilyl-acetylene and 1,4-Bis(trimethylsilyl)-1,3-butadiyne.

82.

R. Beckhaus, M. Wagner, V. V. Burlakov, W. Baumann, N. Peulecke, A. Spannenberg, R. Kempe, U. Rosenthal, Z. Anorg. Allg. Chem. 1998, 624, 129-134. Terminal Alkynes in the Coordination Sphere of Titanocene Complexes - Elementary Steps in Catalytic Dimerizations and Oligomerizations of Alkynes.

81.

S. Pulst, U. Rosenthal, A. Spannenberg, R. Kempe, Z. Krist. 1997, 213, 215-216. Crystal Structure of 2,2-Bis(η5-2,4-cyclopentadien-1-yl)-2-titanium-3-(t-butylethynyl)-4-t-butyl-furan-5-on.

80.

P.-M. Pellny, N. Peulecke, V. V. Burlakov, A. Tillack, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Angew. Chem. 1997, 109, 2728-2730. Angew. Chem. Int. Ed. Engl. 1997, 36, 2515-2617. Doppelte C-C-Einfachbindungsaktivierung und -spaltung bei der Umsetzung von Octatetrainen mit Titanocen- und Zirconocenkomplexen.

79.

P. Arndt, D. Thomas, U. Rosenthal, Tetrahedron Lett. 1997, 38, 5467-5468. Ring-Opening Polymerization of ε-Caprolactone Catalyzed by Titanocene- and Zirconocene Alkyne Complexes.

78.

N. Peulecke, D. Thomas, W. Baumann, U. Rosenthal, Tetrahedron Lett. 1997, 38, 6655-6656. Dehydrocoupling of Silanes Catalyzed by Titanocene and Zirconocene Alkyne Complexes.

77.

V. V. Burlakov, A. I. Yanovsky, Yu. T. Struchkov, V. B. Shur, O. G. Ellert, U. Rosenthal, J. Organomet. Chem. 1997, 542, 105-112. Interaction of Carbon Dioxide with Acetylene Complexes of Titanocene Cp2Ti(RC2R) (R = Ph, SiMe3). Synthesis and Structure of Binuclear σ-Alkenyl- carboxylate Complexes of Titanium(III) Cp2TiC(R)=C(R)COOTiCp2 and unexpected Transformation of These Complexes into Titanafuranone Metallacycles Under the Action of Air Oxygen.

76.

S. Mansel, D. Thomas, C. Lefeber, D. Heller, R. Kempe, W. Baumann, U. Rosenthal, Organometallics 1997, 16, 2886-2890. Stable rac-[1,2-Ethylene-1,1'-bis(η5-tetrahydroindenyl)]-zirconacyclopentanes. Syntheses, X-ray Crystal Structures, Stability, and Catalysis of Ethylene Polymerization.

75.

Review: U. Rosenthal, Spektrum der Wissenschaft, Februar 1997, 89-92. Übergangsmetalle als Katalyse-Werkzeuge: Musterfall sich auszahlender Grundlagenforschung.

74.

A. Tillack, S. Pulst, W. Baumann, H. Baudisch, K. Kortus, U. Rosenthal, J. Organomet. Chem. 1997, 532, 117-123. Hydrosilylierung von symmetrisch disubstituierten Alkinen und Butadiinen mit L2Ni(0)-Butadiin-Komplexen [L = Ph3P, (o-Tol-O)3P] als Katalysatoren.

73.

A. Tillack, C. Lefeber, N. Peulecke, D. Thomas, U. Rosenthal, Tetrahedron Lett. 1997, 38, 1533-1534. The Hydrosilylation of Ald- and Ketimines Catalyzed by Titanocene Complexes.

72.

V. V. Burlakov, N. Peulecke, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, Coll. Czechoslov. Chem. Comm. 1996, 62, 331-336. Reactions of the Coupling Products from Me3SiC≡C-C≡CSiMe3 with Titanocene and Zirconocene.

71.

V. V. Burlakov, N. Peulecke, W. Baumann, A. Spannenberg, R. Kempe, U. Rosenthal, J. Organomet. Chem. 1997, 536-537, 293-297. Reactions of the Phenyl Substituted Five membered Titanacyclocumulene - Unusual Coupling of a 1,4-disubstituted 1,3-butadiyne with two Titanium atoms.

70.

P. Arndt, C. Lefeber, A. Tillack, U. Rosenthal, Chem. Ber. 1996, 129, 1281-1285. Reactions of Lactames with Titanocene- and Zirconocene Alkyne Complexes as Elemental Steps for catalytic anionic Ring-Opening-Polymerization of Lactames.

69.

Book contribution: U. Rosenthal, A. Ohff, C. Lefeber, Max-Planck-Gesellschaft, Jahrbuch 1995, Vandenhoeck & Ruprecht, Göttingen 1996, 713 - 718.

68.

A. Tillack, W. Baumann, A. Ohff, C. Lefeber, A. Spannenberg, U. Rosenthal, J. Organomet. Chem. 1996, 520, 187-193. Intramolekulare Cyclisierung von terminal disubstituierten α*,ϖ-Diinen an Titanocen "Cp2Ti" mit einer nachfolgenden, ungewöhnlichen Cp-Ringöffnung und neuen intramolekularen C-C-Knüpfung.

67.

S. Pulst, P. Arndt, B. Heller, W. Baumann, R. Kempe und U. Rosenthal, Angew. Chem. 1996, 108, 1175-1178. Angew. Chem. Int. Ed. Engl. 1996, 35, 1112-1114. Nickel(0)-Komplexe fünfgliedriger Titana- und Zirconacyclocumulene als Zwischenverbindungen in der C-C-Bindungsspaltung disubstituierter Butadiine.

66.

N. Peulecke, C. Lefeber, A. Ohff, W. Baumann, A. Tillack, R. Kempe, V.V. Burlakov, U. Rosenthal, Chem. Ber. 1996, 129, 959-962. ansa-Titanocene and -Zirconocene η2-Alkyne Complexes. Synthesis, Spectral Characteristics, and X-ray Crystal Structure.

65.

N. Peulecke, A. Ohff, W. Baumann, R. Kempe, U. Rosenthal, J. Organomet. Chem. 1996, 520, 235-239. Influence of Solvents on the Insertion of Methacroleine into Zirconacyclopropenes.

64.

A. Ohff, R. Kempe, W. Baumann, U. Rosenthal, J. Organomet. Chem. 1996, 520, 241-244. Reaktion eines Titanocen-Alkin-Komplexes mit Trialkylammonium-tetraphenylborat - eine neue Darstellungsweise und erste Kristallstrukturanalyse von neutralhaltigen kationischen Titanocen(III)- Komplexen [{Cp2Ti(L)2+}{BPh4-}].

63.

A. Ohff, V. V. Burlakov, U. Rosenthal, J. Mol. Catal. 1996, 108, 119-123. Acetylene Polymerization by Titanocene- and Zirconocene Alkyne Complexes.

62.

C. Lefeber, W. Baumann, A. Tillack, H. Görls, U. Rosenthal, Organometallics 1996, 15, 3486-3490. rac-[1,2-Ethylene-1,1'-bis(η5-tetrahydroindenyl)][η2-bis(trimethylsilyl)-acetylene]-zirconium the First Zirconocene Alkyne Complex without Additional Ligands. Synthesis, Reactions, and X-ray Crystal Structure.

61.

R. Kempe, A. Ohff, U. Rosenthal, Z. Krist. 1996, 211, 495-496- Crystal structure of μ-O-Bis[σ-1,2-bis(trimethylsilyl)vinylzirconocene].

60.

V. V. Burlakov, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov, V. B. Shur, U. Rosenthal, U. Thewalt, J. Organomet. Chem. 1996, 522, 241-247; Interaction of Carbon Dioxide with Bis(trimethylsilyl)acetylene Complex of Permethyl-titanocene. Synthesis and Structure of Binuclear Carbonate Complex of Permethyl-titanocene (Cp*2Ti)2CO3.

59.

N. Peulecke, A. Ohff, A. Tillack, W. Baumann, R. Kempe, V. V. Burlakov U. Rosenthal, Organometallics 1996, 15, 1340-1344; Reactions of Zirconocene Complexes of Bis(trimethylsilyl)acetylene with Benzophenone, Benzaldehyde, Formaldehyde.

58.

A. Ohff, V. V. Burlakov, U. Rosenthal, J. Mol. Catal. 1996, 105, 103; Isomerization by Titanocene- and Zirconocene Alkyne Complexes. 

57.

Review: A. Ohff, S. Pulst, C. Lefeber, N. Peulecke, P. Arndt, V. V. Burlakov, U. Rosenthal, SYNLETT 1996, 111-118; Unusual Reactions of Titanocene- and Zirconocene Generating Complexes.

56.

P. Arndt, C. Lefeber, R. Kempe, U. Rosenthal, Chem. Ber. 1996, 129, 207-211; Ring Enlargement and Ring Opening Reactions of Benzoxazole, Thiazoles and Benzisoxazole by Zirconocene Complexes.

55.

A. Ohff, P. Kosse, W. Baumann, A. Tillack, R. Kempe, H. Görls, V. V. Burlakov, U. Rosenthal, J. Am. Chem. Soc. 1995, 117, 10399-10340, Novel trans-η2-Alkyne Complexes of Titanocene with Strong Si-H-Ti Interactions. Synthesis, Spectral Characteristics, and X-ray Crystal Structure.

54.

U. Rosenthal, C. Lefeber, P. Arndt, A. Tillack, W. Baumann, R. Kempe, V. V. Burlakov, J. Organomet. Chem. 1995, 503, 221-223; Intramolekulare Insertion eines η5-Cyclopentadienyl-Ringes in einem Bis-η5-cyclopentadienyl-titana-cyclopentadien.

53.

V. V. Burlakov, A. Ohff, C. Lefeber, A. Tillack, W. Baumann, R. Kempe, U. Rosenthal, Chem. Ber. 1995, 128, 967-971; The First Titanacyclic Five-Membered Cumulene. Synthesis, Structure, and Reactivity.

52.

C. Lefeber, A. Ohff, A. Tillack, W. Baumann, R. Kempe, V. V. Burlakov, U. Rosenthal, J. Organomet. Chem. 1995, 501, 189-194; Darstellung und regioselektive Reaktionen des phosphinfreien Zirconocen-Alkin-Komplexes Cp2Zr(THF)(tBuC2SiMe3).

51.

C. Lefeber, A. Ohff, A. Tillack, W. Baumann, R. Kempe, V. V. Burlakov, U. Rosenthal, H. Görls, J. Organomet. Chem. 1995, 501, 179-188; Regioselektive Reaktionen der fremdligandfreien Titanocen- Alkin-Komplexe Cp2Ti(RC2SiMe3) (R = Me3Si, Ph, tBu, nBu).

50.

R. Kempe, A. Ohff, U. Rosenthal, Z. Krist. 1995, 210, 707-708; Crystal structure of 1,1-bis-cyclopentadienyl-2,4-bis(trimethylsilyl)-3-(t-butylethynyl)-7-(t-butyl)zirconacyclohepta-2,4,5,6-tetraene.

49.

S. Pulst, P. Arndt, W. Baumann, A. Tillack, W. Baumann, R. Kempe, U. Rosenthal, J. Chem. Soc.; Chem. Commun., 1995, 1753-1754; Formation of the First Heterobimetallic Phosphido-bridged σ,π-Acetylide Complex by Cleavage of the Central C-C-Single bond in PhC≡C-C≡CSiMe3 and of P-C Bond in Ph3P, and Coupling of the Fragments to Ph C≡CSiMe3.

48.

U. Rosenthal, S. Pulst, P. Arndt, A. Ohff, A. Tillack, W. Baumann, R. Kempe, V. V. Burlakov, Organometallics 1995, 14, 2961-2968; Heterobimetallic σ,π-Acetylide Bridged Complexes from Disubstituted 1,3-Butadiynes.

47.

C. Lefeber, P. Arndt, A. Tillack, W. Baumann, R. Kempe, V. V. Burlakov, U. Rosenthal, Organometallics 1995, 14, 3090-3093; Reactions of the Schiff Bases HN=CPh2 and PhN=CHPh with Titanocene- and Zirconocene-Generating Complexes.

46.

U. Rosenthal, S. Pulst, P. Arndt, W. Baumann, A. Tillack, R. Kempe, Z. Naturforsch. 1995, 50b, 368-376, Zum Ligandeneinfluß in neuen Ni(0)-Komplexen disubstituierter Butadiine.

45.

U. Rosenthal, S. Pulst, P. Arndt, W. Baumann, A. Tillack, R. Kempe, Z. Naturforsch. 1995, 50b, 377-384; Zum Substituenteneinfluß in neuen Ni(0)-Butadiin-Komplexen.

44.

U. Rosenthal, A. Ohff, W. Baumann, A. Tillack, H. Görls, V. V. Burlakov, V. B. Shur, Z. Anorg. Allg. Chem. 1995, 621, 77-83; Struktur, Eigenschaften und NMR-spektroskopische Charakterisierung von Cp2Zr(Pyridin)Ni(Me3SiC≡CSiMe3).

43.

B. Marciniec, H. Maciejewski, U. Rosenthal, J. Organomet. Chem. 1994, 484, 147-151; Catalysis of Hydrosilylation Part XXV. Effect of Nickel(0) and Nickel(II)complex Catalysts on Dehydrogenative Silylation, Hydrosilylation and Dimerization of Vinyltriethoxysilane.

42.

U. Rosenthal, C. Nauck, P. Arndt, S. Pulst, W. Baumann, V. V. Burlakov, H. Görls, J. Organomet. Chem. 1994, 484, 81-87; Darstellung und Eigenschaften des Komplexes (dipy)Ni(η2-PhC2SiMe3). Zur Korrelation struktureller Bindungsparameter mit IR- und NMR-spektroskopischen Daten in Übergangsmetall-Alkin-Komplexen.

41.

U. Rosenthal, A. Ohff, W. Baumann, A. Tillack, H. Görls, V. V. Burlakov, V. B. Shur, J. Organomet. Chem. 1994, 484, 203-207; Zirkonadihydrofuran-Komplexe: Darstellung, Struktur und Reaktivitäts-Betrachtungen.

40.

U. Rosenthal, A. Ohff, W. Baumann, R. Kempe, A. Tillack, V. V. Burlakov, Angew. Chem. 1994, 106, 1946-1948, Angew. Chem. Int. Ed. Engl. 1994, 33, 1850-1852; Ungewöhnliche Reaktionen von Acetylendicarbonsäurediestern an Zirkonocenkomplexen.

39.

V. V. Burlakov, A. V. Polyakov, A. I. Yanovsky, Yu. T. Struchkov, V. B. Shur, M. E. Vol'pin, U. Rosenthal, H. Görls, J. Organomet. Chem. 1994, 476, 197-206; Novel Acetylene Complexes of Titanocene and Permethyltitanocene without Additional Ligands. Synthesis, Spectral Characteristics and X-ray Diffraction Study. 

38.

U. Rosenthal, A. Ohff, W. Baumann, R. Kempe, A. Tillack, V. V. Burlakov, Angew. Chem. 1994, 106, 1678-1680, Angew. Chem. Int. Ed. Engl. 1994, 33, 1605-1607; Synthese und Struktur des kleinsten bekannten cyclischen Cumulens: Umsetzung von 1,3-Diinen mit Zirconocenkomplexen.

37.

U. Rosenthal, A. Ohff, W. Baumann, R. Kempe, A. Tillack, V. Burlakov, Organometallics 1994, 13, 2903-2906; Reaction of 1,3-Butadiynes R1C≡C-C≡CR2 with Zirconocene Complexes: Cleavage of the Central C-C Single bond To Form Symmetrically and Usymmetrically Doubly Acetylide-Bridged Metallocene Complexes.

36.

U. Rosenthal, A. Ohff, A. Tillack, W. Baumann, H. Görls, J. Organomet. Chem. 1994, 468, C4-C8;. Zu Reaktionen disubstituierter Butadiine mit Titanocen-Komplexen.

35.

Book contribution: U. Rosenthal, A. Ohff, S. Pulst:, Max-Planck-Gesellschaft, Jahrbuch 1994, Vandenhoeck & Ruprecht, Göttingen 1994, S. 693.

34.

U. Rosenthal, A. Ohff, M. Michalik, H. Görls, V. V. Burlakov, V. B. Shur, Organometallics 1993, 12, 5016-5019; Interaction of the Zirconocene Alkyne Complex Cp2Zr(THF)(Me3SiC2SiMe3) and the Binuclear Zirconium σ-Alkenyl Complex {Cp[μ-(η15-C5H4)]Zr[C(SiMe3)=CH-(SiMe3)]}2 with Carbon Dioxide and Water.

33.

Book contribution: U. Rosenthal, A. Ohff, Max-Planck-Gesellschaft, Jahrbuch 1993, Vandenhoeck & Ruprecht, Göttingen 1993, S. 689.

32.

U. Rosenthal, A. Ohff, M. Michalik, H. Görls, V. V Burlakov, V. B. Shur, Angew. Chem. 1993, 105, 1228-1230, Angew. Chem. Int. Ed. Engl. 1993, 32, 1193-1195; Umwandlung des ersten Zirconocen-Alkin-Komplexes ohne zusätzlichen Phosphan-Liganden in einen zweikernigen σ-Alkenyl-Komplex durch Wasserstoff-Übertragung vom η2-C5H5- zum Alkin-Liganden.

31.

V. V. Burlakov, U. Rosenthal, F. M. Dolgushin, A. I. Yanovski, Yu. T. Struchkov, O. G. Ellert, V. B. Shur, M. E. Vol'pin, Metalloorg. Khim. 1992, 5, 1213-1214 (russ.); Zur Bildung eines zweikernigen Titan(III)- Carbonat-Komplexes bei der Einwirkung von Kohlendioxid auf den Bis(trimethylsilyl)acetylen-Komplex des Permethyltitanocen. 

30.

Book contribution: U. Rosenthal, Max-Planck-Gesellschaft, Jahrbuch 1992, Vandenhoeck & Ruprecht, Göttingen 1992, S. 594.

29.

U. Rosenthal, H. Görls, J. Organomet. Chem. 1992, 439, C36-C41; Die Bildung von [Cp2Ti(C≡CSiMe3)]2 aus Titanocen und 1,4-Bis(trimethylsilyl)-1,3-butadiin.

28.

U. Rosenthal, H. Görls, V. V. Burlakov, V. B. Shur, M. E. Vol'pin, J. Organomet. Chem. 1992, 426, C53-C59; Alkinkomplexe des Titanocen und Permethyltitanocens ohne zusätzliche Liganden. Erste Strukturvergleiche.

27.

U. Rosenthal, G. Oehme, H. Görls, V. V. Burlakov, A. I. Yanovsky, Yu.T. Struchkov, J. Organomet. Chem. 1991, 409, 299-306. Crystal and Molecular Structure of 2-3-η2-(Butyne-1,4-diol)bis(triisopropyl-phosphane)nickel(0) (iPr3P)2Ni(HOCH2-C2-CH2OH). Some Peculiarities of Complexation of Butyne-1,4-diol in Ni(0) Complexes.

26.

U. Rosenthal, G. Oehme, V. V. Burlakov, P. V. Petrovskii, M. E. Vol'pin, J. Organomet. Chem. 1990, 391, 119-122; 13C-{1H}- NMR Studies of Selected Transition Metal Alkyne Complexes.

25.

V. V. Burlakov, U. Rosenthal, R. Beckhaus, Yu. T. Struchkov, G. Oehme, V. B. Shur, M. E. Vol'pin, Organomet. Chem. USSR 1990, 3, 237; New Alkyne Complexes of Titanocene and Permethyltitanocene without Additional Ligands. The First X-ray Diffraction Study of an Alkyne Complex of this Type.

24.

U. Rosenthal, G. Oehme, H. Görls, V. V. Burlakov, A. I. Yanovsky, Yu. T. Struchkov, J. Organomet. Chem. 1990, 390, 113-120; Crystal and Molecular Structure of 2,3-η2-(1,4-dimethoxybut-2-yne)bis(tricyclohexyl-phosphane)nickel(0): (Cy3P)2Ni(MeOCH2-C2-CH2OMe). Influence of Phosphane Ligands on Acetylene Complexation in Nickel(0) Complexes.

23.

U. Rosenthal, G. Oehme, H. Görls, V. V. Burlakov, A. I. Yanovsky, Yu. T. Struchkov, J. Organomet. Chem. 1990, 389, 409-416; Crystal and Molecular Structure of 2,3-η2-(1,4-dimethoxy-but-2-yne)bis(triphenyl-phosphane)-nickel(0): (Ph3P)2Ni(MeOCH2-C2-CH2OMe). Influence of Acetylene Substituents on Acetylene Complexation in Nickel(0) Complexes.

22.

U. Rosenthal, G. Oehme, H. Görls, V. V. Burlakov, A. I. Yanovsky, Yu. T. Struchkov, J. Organomet. Chem. 1990, 389, 251-258. Crystal and Molecular Structure of (η2-acetylenedimethyl-dicarboxylate)-bis(triphenyl-phosphane)nickel(0): (Ph3P)2Ni(MeOOC-C2-COOMe). Influence of Metals on Acetylene Complexation.

21.

D. Walther, D. Braun, W. Schulz, U. Rosenthal, Z. Anorg. Allg. Chem. 1989, 577, 270-282; Selektive Cyclotetramerisierung von Propargylalkohol: katalytische Reaktionen hoher Selektivität und Geschwindigkeit an Nickelkomplexen.

20.

V. V. Burlakov, U. Rosenthal, A. I. Yanovsky, Yu. T. Struchkov, O. G. Ellert, V. B. Shur, M. E. Vol'pin, Organomet. Chem. USSR 1989, 2, 1193; The Interaction of Carbon Dioxide with Ethynyl Complexes of Titanocene. The Synthesis and Structure of Dinuclear Titanium (III) s-vinylcarboxylate Complexes.

19.

D. Walther, D. Braun, W. Schulz, U. Rosenthal, Z. Chem. 1989, 29, 293; Selektive Cyclotetramerisierung von Propargylalkohol; Überraschend hohe Toleranz katalytischer Nickelsysteme gegenüber 'Katalysatorgiften'.

18.

V. V. Burlakov, U. Rosenthal, P. V. Petrovskii, V. B. Shur, M. E. Vol'pin, Organomet. Chem. USSR 1988, 1, 526; A Complex of Titanocene with Bis(trimethylsilyl)acetylene.

17.

U. Rosenthal, H. Görls, J. Organomet. Chem. 1988, 348, 135-139; Structural Comparison of Acetylene Nickel (0) Complexes.

16.

H. Görls, B. Schulz, U. Rosenthal, W. Schulz, Cryst. Res. Technol. 1988, 23, 135-140; Crystal and Molecular Structure of (2-3-η2-Butyne-1,4-diol)-bis(triphenylphosphanenickel(0) Ni[(C6H5)3P]2[C4H6O2].

15.

U. Rosenthal, W. Schulz, H. Görls, Z. Anorg. Allg. Chem. 1987, 550, 169-167; [(C6H5)3P]2Ni(Me3SiC2SiMe3) - Darstellung und Eigenschaften des ersten stabilen Nickel(0)-Komplexes von Bis-trimethylsilyl-acetylen.

14.

W. Schulz, U. Rosenthal, D. Braun, D. Walther, Z. Chem. 1987, 27, 264, Katalytische Cyclotetramerisierung von Propargylalkohol: Aktivität und Selektivität unterschiedlicher Nickelkatalysatoren.

13.

U. Rosenthal, W. Schulz, J. Organomet. Chem. 1987, 321, 103-117; Zusammenhänge zwischen Alkinkomplexierung und - aktivierung in Komplexen des Typs (Ligand)2Ni(Alkin).

12.

U. Rosenthal, W. Schulz, J. Prakt. Chem. 1986, 329, 335-341; Darstellung und Eigenschaften hexasubstituierter Benzenderivate.

11.

W. Schulz, U. Rosenthal, Z. Chem. 1986, 26, 177; Cyclotrimerisierung von 1,4-Dimethoxy-but-2-in an homogenen Komplexkatalysatoren.

10.

U. Rosenthal, W. Schulz, Z. Chem. 1985, 25, 227; Alkinaktivierung an Nickel(0)-Zentren: Stabilitäts- und Reaktivitätsvergleiche an Komplexen des Typs (Ligand)2Ni(Alkin).

9.

U. Rosenthal, Z. Anorg. Allg. Chem. 1984, 513, 151-156; Darstellung und Eigenschaften einiger Nickel(0)-Komplexe mit stickstoffhaltigen Alkinverbindungen.

8.

U. Rosenthal, Z. Anorg. Allg. Chem. 1981, 482, 179-184; Darstellung und Eigenschaften ausgewählter Hydroxy-acetylen- Komplexe des Nickel(0).

7.

H. Zinner, U. Rosenthal, H.-P. Kruse, S. Rosenthal, J. Prakt. Chem. 1978, 320, 625; Synthesen mit 1.2.2.2-Tetrachloräthylisocyanat.

6.

E. Kurras, U. Rosenthal, J. Organomet. Chem. 1978, 160, 35-40; Phosphorylid-Komplexe von σ-Phenyl- und σ-Phenylacetylid-Chrom-Verbindungen.

5.

W.-H. Böhmer, K. Madeja, E. Kurras, U. Rosenthal, Z. Anorg. Allg. Chem. 1979, 458, 69-73; Das Ligandenfeldspektrum des Chrom(III)-tris(dimethylphosphonium-bismethylids).

4.

W.-H. Böhmer, K. Madeja, E. Kurras, U. Rosenthal, Z. Chem. 1978, 18, 453-454; Spektroskopische Untersuchungen an metallorganischen Zweikernkomplexen des Typs M2[(CH2)2P(CH3)2]4(M = CrII, MoII) mit starker Metall-Metall-Wechselwirkung.

3.

E. Kurras, H. Mennenga, G. Oehme, U. Rosenthal, G. Engelhardt, J. Organomet. Chem. 1975, 84, C13-C15; Dimeres Molybdän(II)-Bis(dimethylphosphonium-bismethylid) Mo2[(CH2)2P(CH3)2]4.

2.

E. Kurras, U. Rosenthal, H. Mennenga, G. Engelhardt, Z. Chem. 1974, 14, 161; Dimeres diamagnetisches Chrom(II)-bis(dimethylphosphonium-bismethylid) Cr2[(CH2)2P(CH3)2]4.

1.

E. Kurras, U. Rosenthal, H. Mennenga, G. Oehme, Angew. Chem. 1973, 85, 913-915, Angew. Chem. Int. Ed. Engl. 1973, 12, 854; Synthese von Chrom(III)-tris(dimethylphosphonium-bismethylid).

20.M. H. Al-Hazmi, A. Alqahtani, U. Rosenthal, B. H. Müller, N. Peulecke, M. Harff, A. Wöhl, A. Maiswinkel, H. Bölt, W. Müller; Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene, US 62/028,558 (24.07.2014), WO 2016/012948.
19.A. Wöhl, A. Maiswinkel, H. Bölt, B. H. Müller, W. Müller, N. Peulecke, U. Rosenthal, M. Harff, M. H. Al-Hazmi, A. Alqahtani; Catalyst composition and process for oligomerization of ethylene, EP 13178362.3 (29.07.2013), WO 2015/015402.
18.A. Wöhl, A. Maiswinkel, H. Bölt, B. H. Müller, W. Müller, N. Peulecke, U. Rosenthal, M. Harf, M. H. Al-Hazmi, A. Alqahtani, S. Azam; Method for purifying a crude PNPNH compound, EP 13154780.4 (11.02.2013), WO 2014/122634.
17.U. Rosenthal, A. Alqahtani, S. Azam, B.H. Müller, N. Peulecke, M. Harf, A. Wöhl, A. Maiswinkel, H. Bölt, W. Müller, M. Al-Hazmi; Purification method for a crude PNPNH compound, EP 13154794.5 (11.02.2013), WO 2014/122633.
16.M. H. Al-Hazmi, A. Alqahtani, U. Rosenthal, B. H. Müller, N. Peulecke, M. Harf, A. Wöhl, A. Maiswinkel, H. Bölt, W. Müller; Metalated ligand, catalyst composition and use thereof in the oligomerization of ethylene, EP 13154784.6 (11.02.2013) WO 2014/122632.
15.A. Wöhl, W. Müller, H. Bölt, A. Maiswinkel, U. Rosenthal, B. H. Müller, N. Peulecke, C. Thaller, M. Harf, S. Peitz, F. Mosa, M. H. Al-Hazmi, S. Azam; Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit, EP20110154663 (16.02.2011), WO 2012/110174.
14.P. M. Fritz, H. Bölt, A. Meiswinkel, C. Taube, F. Winkler, V. Göke, W. Müller, A. Wöhl, R. Schneider, U. Rosenthal, H. Fritz, B. H. Müller, N. Peulecke, S. Peitz, B. R. Aluri, M. Al-Hazmi, A. S. Majeed, F. Mosa, A. Al-Dugathier; Method for preparing linear alpha-olefins, EP 09009599.3 (24.07.2009),  WO 2011/009509.
13.A. Wöhl, U. Rosenthal, B. H. Müller, N. Peulecke, S. Peitz, W. Müller, H. Bölt, A. Meiswinkel, B. R. Aluri, M. Al-Hazmi, M. Al-Masned, K. Al-Eidan, F. Mosa; Catalyst composition and process for oligomerization of ethylene, EP 2239056 (09.04.2009), WO 2010/115520.
12.W. Müller, P. M. Fritz, H. Bölt, A. Wellenhofer, F. Winkler, U. Rosenthal, H.-J. Zander, N. Peulecke, B. H. Müller, K.-H. Hofmann, H. Fritz, C. Taube, A. Meiswinkel, R. Schneider, A. Wöhl, V. Aliyev, F. Mosa, M. Al-Hazmi, S. Palackal, A. Al-Ayed, S. Al-Otaibi, M. Zahoor, Method for preparing linear alpha-olefins, EP08001677.7 (30.01.2008), WO 2009/095147.
11.V. Aliyev, M. Al-Hazmi, F. Mosa, U. Rosenthal, B. H. Müller, M. Hapke, N. Peulecke, A. Wöhl, P. M. Fritz, H. Bölt, W. Müller, F. Winkler, A. Wellenhofer; Catalyst for oligomerization of ethylene, method for preparation thereof and process for oligomerization using it, EP 08006851.3 (04.04.2008), WO 2009/121456.
10.V. Aliyev, M. Al-Hazmi, F. Mosa, P. M. Fritz, H. Bölt, A. Wöhl, W. Müller, F. Winkler, A. Wellenhofer, U. Rosenthal, B. H. Müller, M. Hapke, N. Peulecke; Catalyst composition and process for oligomerization of ethylene, EP 07023013.1 (28.11.2007), WO 2009/068157.
9.P. M. Fritz, H. Bölt, A. Wöhl, W. Müller, F. Winkler, A. Wellenhofer, U. Rosenthal, B. H. Müller, M. Hapke, N. Peulecke, M. Al-Hazmi, V. Aliyev, F. Mosa; Catalyst composition and process for di-, tri- and/or tetramerization of ethylene, EP 07013543.9 (11.07.2007), WO 2009/006979.

8.

S. Becke, U. Rosenthal, P. Arndt, W. Baumann, A. Spannenberg, Katalysatorsystem zur Olefinpolymerisation, DE 101 10 227 (02.03.2001)

7.

S. Becke, U. Rosenthal, P. Arndt, W. Baumann, A. Spannenberg, Zusammernsetzung auf  Basis von Monofluormetallkomplexen, DE 100 53 486.4 (27.10.2000), WO 0234758 

6.

S. Becke, U. Rosenthal, Zusammensetzung auf Basis von fluorhaltigen Metallkomplexen, DE 199 32 409 (14.07.1999), WO 0105850 

5.

W. Schulz, U. Rosenthal, Verfahren zur selektiven katalytischen Mischzyclisierung von Acetylen mit Nitrilen, DD 2968238 vom 28.11.1986.

4.

W. Schulz, U. Rosenthal, Verfahren zur selektiven katalytischen Tetramerisierung von Propargylalkohol zu Tetrakis-hydroxymethyl-cyclooctatetraen, DD 2948234 vom 30.09.1986.

3.

W. Schulz, U. Rosenthal, Verfahren zur katalytischen Cyclisierung von Alkinen, DD 2795916 vom 12.08.1985.

2.

U. Rosenthal, Katalytische Cyclotrimerisierung von But-2-in-1,4-diol-Abkömmlingen zu hexasubstituierten Benzenderivaten, DD 2425443 vom 16.08.1982.

1.

U. Rosenthal, Verfahren zur Herstellung von Hexamethylolbenzen, DD 2425435 vom 16.08.1982.