As feedstock used essentially olefins in order to refine further a substantial unused part of such. Butane in the C4 stream from a cracker are from petrochemicals remains unused for chemical transformation. Therefore, we investigate dehydrogenation of alkanes to olefins.
S. Fritschi, W. Korth, J. Julis, D. Kruse, H. Hahn, R. Franke, I. Fleischer, A. Dutta Chowdhury, N. Weding, R. Jackstell, M. Beller, A. Jess, 2015, Chemie Ingenieur Technik ,87,10,1313-1326, "Synthesis of Aliphatic Aldehydes from Alkanes and Carbon Dioxide: Valeraldehyde from Butane and CO2 - Feasibility and Limitations“
A. D. Chowdhury, J. Julis, K. Grabow, B. Hannebauer, U. Bentrup, M. Adam, R. Franke, R. Jackstell, M. Beller, ChemSusChem, 2015, 8(2), 323-330, “Photocatalytic Acceptorless Alkane Dehydrogenation: Scope, Mechanism and Conquer the Deactivation with Carbon Dioxide"
A. D. Chowdhury, N. Weding, J. Julis, R. Franke, R. Jackstell, M. Beller , Angew. Chem. Int. Ed. 2014, 53, 6477-6481 “Towards a Practical Development of Light Driven Acceptorless Alkane Dehydrogenation”