Publications – Prof. Dr. Marko Hapke




Thiel I, Jiao H, Spannenberg A, Hapke M. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 763–764, 60-64. Decomposition mechanism of a cobalt-coordinated phosphite–olefin ligand under irradiation.
40.Thiel I and Hapke M. REVIEWS IN INORGANIC CHEMISTRY, 2014, 34, 217-245. The broad diversity of CpCo(I) complexes.
39.Thiel I, Hapke M. JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, 2014, 383–384, 153-158. The first solid-supported Cp'Co(I)-catalyst for the synthesis of pyridines.
38.Guo CH, Wu HS, Hapke M, Jiao H JOURNAL OF ORGANOMETALLIC CHEMISTRY 2013, 748, 29-35. Theoretical Studies on Acetylene Cyclotrimerization into Benzene Catalyzed by CpIr Fragment.
37.Hapke M, Tzschucke CC ANGEWANDTE CHEMIE – INTERNATIONAL EDITION 2013, 52, 3317-3319. Achieving Enantioselectivity with Chiral Cyclopentadienylrhodium Complexes.
36.Heller B, Hapke M, Fischer C, Andronova A, Stary I, Stara IG JOURNAL OF ORGANOMETALLIC CHEMISTRY 2013, 723, 98–102. Chiral Cobalt1 and Nickel0 Complexes in the Synthesis of Nonracemic Helicenes through the Enantioselective [2+2+2] Cyclotrimerisation of Alkynes.
35.Thiel I, Jiao H, Spannenberg A, Hapke M CHEMISTRY – A EUROPEAN JOURNAL 2013, 19, 2548-2554. Fine-Tuning the Reactivity and Stability by Systematic Ligand Variations in CpCo(I) Complexes as Catalysts for [2+2+2] Cycloaddition Reactions.
33.Thiel I, Hapke M ANGEWANDTE CHEMIE – INTERNATIONAL EDITION 2013, 52, 5916-5918. Computational Studies and Experimental Results – An Example of Excellent Teamwork in Studying Carbocyclization.

Thiel I, Lamač M, Jiao H, Spannenberg A, Hapke M ORGANOMETALLICS 2013, 32, 3415-3418. Synthesis and Catalytic Activity of [Cp’Co(COD)] Complexes Bearing Pendant N-Containing Groups.

31.Thiel I, Spannenberg A, Hapke M CHEMCATCHEM 2013, 5, 2865-2868. Synthesis of Air-Stable and Recyclable CpCoI-Complexes.
30.F. Fischer, P. Jungk, N. Weding, A. Spannenberg, H. Ott, M. Hapke, Eur. J. Org. Chem. 2012, 5828-5838. Diastereomeric Atropisomers from a Chiral Diyne by Co(I)-Catalyzed Cyclotrimerization.
29.N. Weding, A. Spannenberg, R. Jackstell, M. Hapke, Organometallics 2012, 31, 5660-5663. Formation and Reactivity of a Co4-μ-Alkyne Cluster from a Co(I)-Alkene Complex.
28.K. Kral, M. Hapke, Tetrahedron Lett. 2012, 53, 2856-2859. Investigations on the synthesis of monoarylated diynes by monoprotection/cross-coupling/deprotection approach.
27.N. Weding, Jackstell, H. J. Jiao, A. Spannenberg, M. Hapke, Advanced Synthesis & Catalysis 2011, 353, 3423-3433. Synthesis of Group 9 Metal-Olefin Complexes with Identical Ligand Framework and Comparison on their Catalytic Activity in [2+2+2] Cycloaddition and other Addition Reactions.

N. Weding, M. Hapke, Chem. Soc. Rev. 2011, 40, 4525-4538. Preparation and synthetic applications of alkene complexes of group 9 transition metals in [2+2+2] cycloaddition reactions.


K. Kral, M. Hapke, Angew. Chem. 2011, 123, 2482-2483; Angew. Chem. Int. Ed. 2011, 50, 2434-2435. Metal-free Cyclotrimerization for the De Novo Synthesis of Pyridines.


M. Hapke, K. Kral, A. Spannenberg, Synthesis 2011, 642-652. On the Synthesis of Arylpropiolic Acid ad Investigations towards the Formation of Vinyl Chlorides by HCl Addition During Esterification Reactions.


M. Hapke, N. Weding, A. Spannenberg, Organometallics 2010, 29, 4298-4304. Highly Reactive Cyclopentadienyl(I) Olefin Complexes.


M. Hapke, N. Weding, A. Spannenberg, Acta Cryst. 2010, E66, m1031. Bis(dimethyl sulfoxide)hydridobis(triphenylphosphane)cobalt(I).


M. Hapke, C. Fischer, K. Kral, A. Spannenberg, A. Gutnov, D. Redkin, B. Heller, J. Org. Chem. 2010, 75, 3993-4003. Asymmetric Synthesis of Axially Chiral 1-Aryl-5,6,7,8-tetrahydroquinolines by Cobalt-Catalyzed [2+2+2] Cycloaddition Reaction of 1-Aryl-1,7-octadiynes and Nitriles.


K. R. Sawyer, J. F. Cahoon, J. E. Shanoski, E. A. Glascoe, M. F. Kling, J. P. Schlegel, M. C. Zoerb, M. Hapke, J. F. Hartwig, C. E. Webster, and C. B. Harris, J. Am. Chem. Soc. 2010, 132, 1848-1859. Time-resolved IR Studies on the Mechanism for the Functionalization of Primary C–H Bonds by Photoactivated Cp*W(CO)3(Bpin).


M. Hapke, A. Gutnov, N. Weding, A. Spannenberg, C. Fischer, C. Benkhäuser-Schunk, B. Heller, Eur. J. Org. Chem. 2010, 509-514. Use of the Diels-Alder Cycloaddition of Tetracyclone and Internal Aryl Acetylenes for the Synthesis of Functionalized Atropochiral Biaryls.

18.B. R. Aluri, N. Peulecke, B. H. Müller, S. Peitz, A. Spannenberg, M. Hapke, U. Rosenthal, Organometallics 2010, 29, 226-231. Synthesis, Coordination Chemistry, and Catalysis of the First 1,2-Bis(diphenylphosphino)-1,2-diphenylhydrazine, Ph2PN(Ph)N(Ph)PPh2.
17.J. Bunzen, M. Hapke, A. Lützen, Eur. J. Org. Chem. 2009, 3885-3894. The Influence of Different Spacer Lengths on the Selectivity of Self-Assembly Processes of Bis(bipyridine)-BINOL Helicates.

M. Hapke, A. Wöhl, S. Peitz, A. Spannenberg, U. Rosenthal, Acta Cryst. 2009, E65, m357; trans-Di-m-acetato-[m-N,N-bis(diphenylphosphino)aniline]bis-[chloridomolybdenum(II)] (Mo-Mo)-dichloromethane-tetrahydrofuran (1/0.3/1.7).


M. Hapke, A. Wöhl, S. Peitz, B. H. Müller, A. Spannenberg, U. Rosenthal, Acta Cryst. 2009, E65, m252. [N,N-bis(diphenylphosphino)isopropylamine]dibromidonickel(II)


M. Hapke, A. Spannenberg, Acta Cryst. 2009, E65, m93. (h5-Cyclopentadienyl)bis(triphenylphosphane)-cobalt(I)-toluene-n-hexane (1/0.20/0.25)).


M. Hapke, L. Brandt, A. Lützen, Chem. Soc. Rev. 2008, 37, 2782-2797. Versatile Tools in the Construction of Substituted 2,2'-Bipyridines - Cross-coupling Reactions with Tin, Zinc and Boron Compounds.


T. Schmidt, Z. Dai, H.-J. Drexler, M. Hapke, A. Preetz, D. Heller, Chem. Asian J. 2008, 3, 1170-1180. The Major/Minor Concept: Dependence of the Selectivity of Homogeneously Catalyzed Reactions on Reactivity Ratio and Concentration Ratio of the Intermediates.


S. Enthaler, G. Erre, K. Junge, K. Schröder, D. Addis, D. Michalik, M. Hapke, D. Redkin, M. Beller, Eur. J. Org. Chem. 2008, 3352-3362. Iridium-Catalyzed Hydrogenation of β-Dehydroamino Acid Derivatives Using Monodentate Phosphoramidites.


B. Heller, D. Redkin, A. Gutnov, C. Fischer, W. Bonrath, R. Karge, M. Hapke, Synthesis 2008, 69-74. Synthesis of Chiral Pyridyl Alcohols using a Two-Step Catalytic Approach.


M. Hapke, H. Staats, I. Wallmann, A. Lützen, Synthesis 2007, 2711-2719. Synthesis of Amino-Functionalized 2,2’-Bipyridines.


B. Heller, M. Hapke, Chem. Soc. Rev. 2007, 36, 1025-1196. The fascinating Construction of Pyridine Ring Systems by Transition Metal-Catalysed [2+2+2] Cycloaddition Reactions.


T. M. Boller, J. M. Murphy, M. Hapke, T. Ishiyama, N. Miyaura, J. F. Hartwig, J. Am. Chem. Soc. 2005, 127, 14263-14278. Mechanism of the Mild Functionalization of Arenes by Diboron Reagents Catalyzed by Iridium Complexes. Intermediacy and Chemistry of Bipyridine-Ligated Iridium Tris Boryl Complexes.


M. Albrecht, I. Janser, A. Lützen, M. Hapke, R. Fröhlich, P. Weis, Chem. Eur. J. 2005, 11, 5742-5748. 5,5'-Diamino-2,2'-bipyridine: A versatile building block for the synthesis of bipyridine/catechol ligands which form homo- and heteronuclear helicates.


J. F. Hartwig, K. S. Cook, M. Hapke, C. D. Incarvito, Y. Fan, C. E. Webster, M. B. Hall, J. Am. Chem. Soc. 2005, 127, 2538-2552. Rhodium Boryl Complexes in the Catalytic, Terminal Functionalization of Alkanes.


A. Lützen, M. Hapke, H. Staats, J. Bunzen, Eur. J. Org. Chem. 2003, 3948-3957;  Synthesis of substituted 2,2'-bipyridines, 2. Synthesis of differently disubstituted 2,2'-bipyridines by a modified Negishi cross-coupling reaction.


A. Lützen, M. Hapke, S. Meyer, Synthesis 2002, 2289-2295. Synthesis of Bis(BINOL) substituted 2,2'-Bipyridines and their Late Transition Metal Complexes.


A. Lützen, M. Hapke, Eur. J. Org. Chem. 2002, 2292-2297. Synthesis of 5-Substituted 2,2'-Bipyridines from Substituted 2-Chloropyridines by a Modified Negishi Cross-Coupling Reaction.


A. Lützen, M. Hapke, J. Griep-Raming, D. Haase, W. Saak, Angew. Chem. 2002, 114, 2190-2194. Angew. Chem. Int. Ed. 2002, 41, 2086-2089. Synthesis and stereoselective self-assembly of double- and triple-stranded helicates.


U. Rosenthal, V. V. Burlakov, P. Arndt, A. Spannenberg, U. Jäger-Fiedler, M. Klahn, M. Hapke, "Reactions of C-F bonds with Titanocene and Zirconocene" in From Secondary Interaction via Bond Cleavage to Catalysis in Activating Unreactive Bonds (Eds. C. Bolm and F. E. Hahn), Wiley-VCH, 2008.

3.M. Hapke, Catalytic Arylation Methods. From the Academic Lab to Industrial Processes. By Anthony J. Burke and Carolina Silva Marques, Angew. Chem. Int. Ed.2015, 54, 14618-14619.


M. Hapke, Modern Arylation Methods (Ed. Lutz Ackermann), Angew. Chem. 2009, 121, 6898-6899; Angew. Chem. Int. Ed. 2009, 48, 6768.


M. Hapke, Catalysis - Concepts and Green Applications (by Gadi Rothenberg), ChemSusChem 2008, 1, 1026.