Publications – PD Dr. Torsten Beweries

53.Klahn M and Beweries T. REVIEWS IN INORGANIC CHEMISTRY, 2014, 34, 177–198. Organometallic water splitting – from coordination chemistry to catalysis.
52.Godemann C, Barsch E, Spannenberg A, Ludwig R, and Beweries T. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 2014, 4068-4072. Synthesis and Characterisation of Bridged Titanocene Oxido Complexes and Their Reactions with Water.
51.Dura L, Spannenberg A, and Beweries T. ACTA CRYSTALLOGRAPHICA, SECTION E: STRUCTURE REPORTS ONLINE, 2014, 70, 533-535. Crystal structure of tricarbonyl(N-diphenylphosphanyl-N,N'-diisopropyl-P-phenylphosphonous diamide-ĸ2 P,P')cobalt(I) tetracarbonylcobaltate(-I) toluene 0.25-solvate.
50.D. Hollmann, K. Grabow, H. Jiao, M. Kessler, A. Spannenberg, T. Beweries, U. Bentrup, A. Brückner, Chem. Eur. J. 2013, 19, 13705. Hydrogen Production by Water Reduction with Cp*2Ti(OTf): Identifying Elemental Mechanistic Steps by combined in situ FTIR and in situ EPR Spectroscopy supported by DFT calculations.
49.J. Thomas, M. Klahn, A. Spannenberg, T. Beweries, Dalton Trans. 2013, 42, 14668. Group 4 metallocene catalysed full dehydrogenation of hydrazine borane.
48.M. Ruhmann, A. Spannenberg, A. Villinger, A. Schulz, T. Beweries, Z. Anorg. Allg. Chem. 2013, 639, 1717; Reactions of Titanocene with Triazines and Dicyandiamide: Formation of Novel Di- and Trinuclear Metallacyclic Complexes.
47.T. Beweries, U. Rosenthal, Nature Chem. 2013, 5, 649; Metallacycles. Breaking the Rules.
46.M. Haehnel, S. Hansen, A. Spannenberg, T. Beweries, Acta Cryst. 2013, E69, m346. Bis(η5-cyclopentadienyl)-bis(bis(2,2,2-trifluoroethoxy)phosphino)methylamine-P,P′-titanium(II).
45.M. Kessler, S. Hansen, C. Godemann, A. Spannenberg, T. Beweries, Chem. Eur. J. 2013, 19, 6350. Synthesis and Structures of ansa-Titanocene Complexes with Diatomic Bridging Units for Overall Water Splitting.
44.J. Djamil, S. A. Segler, A. Dabrowski, W. Bensch, A. Lotnyk, U. Schürmann, L. Kienle, S. Hansen, T. Beweries, Dalton Trans. 2013, 42, 1287. Influence of Carbon Content in Molybdenum Sulfides MoSxCy Obtained by Thermal Decomposition On Photocatalytic Hydrogen Generation.
43.JA. Kruth, S. Hansen, T. Beweries, V. Brüser, K.-D. Weltmann, ChemSusChem 2013, 6, 152. Plasma Synthesis of Polymer-Capped Organic Dye-Sensitised Anatase Nanopowders for Visible Light-driven Hydrogen Evolution.
42.S. Hansen, M.-M. Pohl, M. Klahn, A. Spannenberg, T. Beweries, ChemSusChem 2013, 6, 92. Investigation and Enhancement of the Stability and Performance of Water Reduction Systems based on cyclometalated Iridium(III) complexes.
41.T. Beweries, M. Haehnel, U. Rosenthal, Catal. Sci. Technol. 2013, 2, 18. Recent advances in the chemistry of heterometallacycles of group 4 metallocenes.
40.M. Haehnel, M. Ruhmann, O. Theilmann, S. Roy, T. Beweries, P. Arndt, A. Spannenberg, A. Villinger, E. D. Jemmis, A. Schulz, U. Rosenthal, J. Am. Chem. Soc. 2012, 134, 15979. Reactions of Titanocene Bis(trimethylsilyl)acetylene Complexes with Carbodiimides – An Experimental and Theoretical Study of Complexation vs. C−N Bond Activation.
39.K. Kaleta, F. Strehler, A. Hildebrandt, T. Beweries, P. Arndt, T. Rüffer, A. Spannenberg, H. Lang, U. Rosenthal, Chem. Eur. J. 2012, 18, 12672. Synthesis and Characterization of Multiferrocenyl Substituted Group 4 Metallocene Complexes (VIP manuscript).
38.M. Haehnel, S. Hansen, A. Spannenberg, P. Arndt, T. Beweries, U. Rosenthal, Chem. Eur. J. 201218, 10546. Highly Strained Heterometallacycles of Group 4 Metallocenes with Bis(diphenylphosphino)amide-Ligands (VIP manuscript, Cover picture).
37.K. Kaleta, M. Kessler, T. Beweries, P. Arndt, A. Spannenberg, U. Rosenthal, Eur. J. Inorg. Chem. 2012, 3388. Different Inertness of Titanocene [Cp2Ti] and Decamethyltitanocene [Cp*2Ti] in Reactions with N,N-Bis(trimethylsilyl)sulfurdiimide: Elimination of Tetramethylfulvene and Formation of Half-Titanocene Complexes.
36.M. Kessler, S. Schüler, D. Hollmann, M. Klahn, T. Beweries, A. Spannenberg, A. Brückner, U. Rosenthal, Angew. Chem. 2012, 124, 6377; Angew. Chem. Int. Ed. 2012, 51, 6272. Photo-assisted Ti−O activation in a decamethyltitanocene dihydroxido complex – Insights into the elemental steps of water splitting (VIP manuscript, Cover picture).
35.S. Roy, E. D. Jemmis, A. Schulz, T. Beweries, U. Rosenthal, Angew. Chem. 2012, 124, 5442; Angew. Chem. Int. Ed. 2012, 51, 5347. Theoretical Evidence of the Stabilization of an Unusual Four-Membered Metallacycloallene by a Transition-Metal Fragment.
34.

S. Hansen, M. Klahn, T. Beweries, U. Rosenthal, ChemSusChem 2012, 5, 656. An intermolecular heterobimetallic system for photocatalytic water reduction.

33.R. R. Aysin, L. A. Leites, V. V. Burlakov, V. B. Shur, T. Beweries, U. Rosenthal, Eur. J. Inorg. Chem. 2012, 922. Peculiarities of the vibrational spectra and electronic structure of the five-membered metallacyclocumulenes of the group 4 metals.
32.K. Kaleta, M. Ruhmann, O. Theilmann, S. Roy, T. Beweries, P. Arndt, A. Villinger, E. D. Jemmis, A. Schulz, U. Rosenthal, Eur. J. Inorg. Chem. 2012, 611. Experimental and Theoretical Study of Unusual Four-Membered Metallacycles from Reactions of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes with the Sulfurdiimide Me3SiN=S=NSiMe3 (Cover picture).
31.T. Beweries, J. Thomas, M. Klahn, D. Heller, A. Schulz, U. Rosenthal, ChemCatChem 2011, 3, 1865. Catalytic and Kinetic Studies of the Dehydrogenation of Dimethylamine Borane with an i-Pr Substituted Titanocene Catalyst.
30.T. Beweries, R. Kuzora, U. Rosenthal, A. Schulz, A. Villinger, Angew. Chem. 2011, 123, 9136. Angew. Chem. Int. Ed. 2011, 50, 8974. [P(µ-NTer)]2: A Biradicaloid That Is Stable at High Temperature (“Hot-Paper”).
29.T. Beweries, L. Brammer, N. A. Jasim, J. E. McGrady, R. N. Perutz, A. C. Whitwood, J. Am. Chem. Soc. 2011, 133, 14338. Energetics of Halogen Bonding of Group 10 Metal Fluoride Complexes.
28.T. Beweries, S. Hansen, M. Kessler, M. Klahn, U. Rosenthal, Dalton Trans. 2011, 40, 7689. Catalytic Dehydrogenation of Dimethylamine-Borane by Group 4 Metallocene Alkyne Complexes and Homoleptic Amido Compounds (Inside cover picture).
27.S. Roy, E. D. Jemmis, M. Ruhmann, A. Schulz, K. Kaleta, T. Beweries, U. Rosenthal, Organometallics 2011, 30, 2670. Theoretical Studies on the Structure and Bonding of Metalla-cyclocumulenes, –cyclopentynes and –cycloallenes.
26.K. Kaleta, M. Ruhmann, O. Theilmann, T. Beweries, S. Roy, P. Arndt, A. Villinger, E. D. Jemmis, A. Schulz, U. Rosenthal, J. Am. Chem. Soc. 2011, 133, 5463. Reactions of Group 4 Metallocene Alkyne Complexes with Carbodiimides: Experimental and Theoretical Studies of the Structure and Bonding of Five-Membered Hetero-Metallacycloallenes.
25.V. V. Burlakov, K. Kaleta, T. Beweries, P. Arndt, W. Baumann, A. Spannenberg, V. B. Shur, U. Rosenthal, Organometallics 2011, 30, 1157. Reactions of Five-membered Metallacyclocumulenes Cp2M(η4-t-Bu-C4-t-Bu) (M = Ti, Zr) with Diisobutylaluminum Hydride.
24.M. Kessler, S. Hansen, D. Hollmann, M. Klahn, T. Beweries, A. Spannenberg, A. Brückner, U. Rosenthal, Eur. J. Inorg. Chem. 2011, 627. Synthesis of Cp*2Ti(OTf) and Its Reaction with Water.
23.O. Theilmann, M. Ruhmann, A. Villinger, A. Schulz, W. W. Seidel, K. Kaleta, T. Beweries, P. Arndt, U. Rosenthal, Angew. Chem. 2010, 122, 9469. Angew. Chem. Int. Ed. 2010, 49, 9282; [Cp2Ti(III)(NCy)2C–Ti(III)Cp2]: A Transient Titanocene Carbene Complex?
22.C. Fischer, T. Beweries, A. Preetz, H.-J. Drexler, W. Baumann, S. Peitz, U. Rosenthal, D. Heller, Catalysis Today 2010, 155, 282. Kinetic and mechanistic investigations in homogeneous catalysis using operando UV/vis spectroscopy.
21.K. Kaleta, P. Arndt, T. Beweries, A. Spannenberg, O. Theilmann, U. Rosenthal, Organometallics 2010, 29, 2604. Reactions of Group 4 Metallocene Alkyne complexes with Azobenzene – Formation of Diazametallacyclopropanes and N=N Bond Activation.
20.V. V. Burlakov, T. Beweries, K. Kaleta, V. S. Bogdanov, P. Arndt, W. Baumann, A. Spannenberg, V. B. Shur, U. Rosenthal, Organometallics 2010, 29, 2367. Reactions of the Five-membered Hafnacyclocumulene Cp2Hf(η4-t-Bu-C4-t-Bu) with the Lewis Acids Tris(pentafluorophenyl)borane and Diisobutylaluminum hydride.
19.T. Beweries, A. Spannenberg, U. Rosenthal, Z. Kristallogr. NCS 2010, 225, 191. Crystal structure of bis(pentamethylcyclopentadienyl)(1-tert-butylisocyanido)-2-trimethylsilyl-3-[(trimethylsilyl)ethynyl]hafnacyclopropene, (C10H15)2Hf(C5H9N)(C10H18Si2).
18.T. Beweries, A. Spannenberg, U. Rosenthal, Z. Kristallogr. NCS 2010, 225, 188. Crystal structure of 1,1-bis(pentamethylcyclopentadienyl)-(4,4’-di-tert butylbipyridyl)hafnium(IV) – hexane (1:0.5), Hf(C10H15)2(C18H24N2) · 0.5C6H14.
17.V. V. Burlakov, T. Beweries, V. S. Bogdanov, P. Arndt, W. Baumann, A. Spannenberg, K. A. Lyssenko, V. B. Shur, U. Rosenthal, Organometallics 2009, 28, 2864. Synthesis and Isolation of Di-n-butylhafnocene and Its Application as a Versatile Starting Material for the Synthesis of New Hafnacycles.
16.T. Beweries, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Eur. J. Inorg. Chem. 2009, 1456. Synthesis of Hafnacyclopentanes from Hafnocene Alkyne Complexes: Influence of Styrene Substituents on the C-C Coupling Regioselectivity.
15.T. Beweries, C. Fischer, S. Peitz, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, D. Heller, U. Rosenthal, J. Am. Chem. Soc. 2009, 131, 4463. Combination of Spectroscopic Methods: in situ NMR and UV/Vis Measurements to understand the Formation of Group 4 Metallacyclopentanes from the corresponding Metallacyclopropenes.
14.T. Beweries, V. V. Burlakov, U. Rosenthal, A. Spannenberg, Z. Kristallogr. NCS 2009, 224, 95. Crystal structure of rac-[1,2-ethylene-bis(η5-4,5,6,7-tetrahydroindenyl)]-1-hafna-4,5-bis(trimethylsilyl)furan-3-one-tris(pentafluorophenyl)borane, (C20H24)Hf(Me3SiC2SiMe3CO2)B(C6F5)3.
13.T. Beweries, V. V. Burlakov, U. Rosenthal, A. Spannenberg, Z. Kristallogr. NCS 2009, 224, 93. Crystal structure of 1,1-bis(pentamethylcyclopentadienyl)-4,5-bis(trimethylsilyl)-1-hafnafuran-3-one, Hf(C10H15)2(Me3SiC2SiMe3CO2).

12.

V. V. Burlakov, V. S. Bogdanov, K. A. Lyssenko, P. V. Petrovskii, T. Beweries, P. Arndt, U. Rosenthal, V. B. Shur, Russ. Chem. Bull. Int. Ed. 2008, 57, 1294. First structurally characterized five-membered hafnacyclocumulene Cp2Hf(η4-t-Bu-C4-t-Bu).

11.

T. Beweries, V. V. Burlakov, S. Peitz, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2008, 27, 3954. Synthesis and Reactions of Cp*2Hf(η2-PhC2SiMe3) with Water and CO2.

10.

T. Beweries, V. V. Burlakov, S. Peitz, M. A. Bach, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2007, 26, 6827. Reactions of Decamethylhafnocene with 1,3-Butadiynes: Formation of Hafnacyclocumulenes and C−H Activation at Pentamethylcyclopentadienyl Ligands.

9.

M. A. Bach, T. Beweries, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2007, 26, 4592. Migratory Insertion of an Isocyanide into 1-Zirconacyclopent-3-ynes.

8.

T. Beweries, U. Jäger-Fiedler, M. A. Bach, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2007, 26, 3000. Ring Opening Reactions of Tetrahydrofurane versus Alkyne Complexation by Group 4 Metallocene Complexes as a general Problem in Synthesis and Reactions of Metallocene Bis(trimethylsilyl)acetylene Complexes.

7.

T. Beweries, V. V. Burlakov, M. A. Bach, S. Peitz, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, B. Pathak, E. D. Jemmis, Angew. Chem. 2007, 119, 7031. Angew. Chem. Int. Ed. 2007, 46, 6907. Tandem Si-C and C-H Activation for Decamethylhafnocene and Bis(trimethylsilyl)acetylene (VIP manuscript, Cover picture).

6.

A. Spannenberg, M. A. Bach, T. Beweries, U. Rosenthal, Z. Kristallogr. NCS 2007, 222, 189. Crystal structure of 3,3-bis(tert-butyl-cyclopentadienyl)-bicyclo[3.1.0]hex-3-zircona-1(5)-ene-6-nickela-6,6-bis(triphenylphosphine), (C9H13)2 (ZrC4H4)Ni(C18H15P)2.

5.

A. Spannenberg, T. Beweries, M. A. Bach, U. Rosenthal, Z. Kristallogr. NCS 2007, 222, 187. Crystal structure of µ-oxo-Bis{bis(cyclopentadienyl)[1,2-bis(trimethylsilyl)ethenyl]hafnium}, C36H58Hf2Si4O.

4.

U. Rosenthal, V. V. Burlakov, M. A. Bach, T. Beweries, Chem. Soc. Rev. 2007, 36, 719. Five-Membered Metallacycles of Titanium und Zirconium – Attractive Compounds for Organometallic Chemistry and Catalysis (Cover picture).

3.

T. Beweries, V. V. Burlakov, M. A. Bach, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2007, 26, 247. Complexation of Bis(trimethylsilyl)acetylene by Decamethylhafnocene To Give the Hafnacyclopropene Cp*2Hf(η2-Me3SiC2SiMe3): An Unusually Strong Metal-Alkyne Interaction.

2.

T. Beweries, M. A. Bach, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, Organometallics 2007, 26, 241. Synthesis of ansa-Dimethylsilanediyl-dicyclopentadienyl-zirconacyclopent-3-yne, Me2Si(η5-C5H4)2Zr(η4-H2C4H2), and Its Reactions with Ni(0) and B(C6F5)3.

1.

M. A. Bach, T. Beweries, V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, W. Bonrath, Organometallics 2005, 24, 5916. Reactions of 1-Titana- and 1-Zirconacyclopent-3-ynes with Tris(pentafluorophenyl)borane. 

1.T. Beweries, U. Rosenthal, Group 4 Metallocene Complexes with Bis(trimethylsilyl)acetylene, in: Science of Synthesis Knowledge Updates 2011/4, D. G. Hall, K. Ishihara, J. J. Li, I. Marek, M. North, E. Schaumann, S. M. Weinreb, M. Yus (vol. eds.), 2011, Stuttgart.